Preparation of magnetic Fe3O4/SiO2/Bi2WO6 microspheres and their application in photocatalysis

被引:42
|
作者
Chen, Su-Hua [1 ]
Yin, Zhen [1 ]
Luo, Sheng-Lian [1 ]
Au, Chak-Tong [1 ,2 ]
Li, Xue-Jun [1 ]
机构
[1] Nanchang Hangkong Univ, Key Lab Jiangxi Prov Ecol Diag Remediat & Pollut, Nanchang 330063, Peoples R China
[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
关键词
Magnetic materials; Chemical synthesis; X-ray diffraction; Electron diffraction; Catalytic properties; OXIDATION; DYES; REMOVAL; BI2WO6;
D O I
10.1016/j.materresbull.2012.11.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetic Fe3O4/SiO2/Bi2WO6 microspheres with photocatalytic properties have been synthesized using a silica layer for "bonding" (adhering Bi2WO6 to Fe3O4). The morphology, composition and magnetic properties of the Fe3O4/SiO2/Bi2WO6 composites were characterized by X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, vibrating sample magnetometry, and BET surface area analysis. The activity of the material in photocatalytic decoloration of aqueous rhodamine B (RhB) solution under visible light was evaluated. The results showed that Bi2WO6 combined well with the magnetic Fe3O4/SiO2 nanoparticles. The Fe3O4/SiO2/Bi2WO6 composites were spherical in shape, having a mean size of 2 pm. The spent catalyst could be recycled with only slight decline in catalytic activity. It is envisaged that the stability, reusability, and magnetic nature of the Fe3O4/SiO2/Bi2WO6 catalyst warrants its application in photocatalysis. (C) 2012 Published by Elsevier Ltd.
引用
收藏
页码:725 / 729
页数:5
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