trans-bis(4-aminopyridine-κN)bis(succinimidato-κN)copper(II) dihydrate

被引:0
作者
Akitsu, T [1 ]
Einaga, Y [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词
D O I
10.1107/S1600536806006209
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu(C4H4NO2)(2)(C5H6N2)(2)]center dot 2H(2)O, has its metal atom in a square-planar trans-[CuN4] coordination environment; the Cu-II atom lies on a center of symmetry. Both succinimidate and 4-aminopyridine ligands behave as monodentate ligands, which coordinate through deprotonated imidate and pyridine ( not amino) N atoms, respectively. The 4-aminopyridine is the first ligand in such Cu-II complexes containing two different N atoms to take potentially different coordination modes.
引用
收藏
页码:M625 / M627
页数:3
相关论文
共 18 条
[11]   ELECTRONIC PROPERTIES AND STEREOCHEMISTRY OF MONO-NUCLEAR COMPLEXES OF COPPER(II) ION [J].
HATHAWAY, BJ ;
BILLING, DE .
COORDINATION CHEMISTRY REVIEWS, 1970, 5 (02) :143-&
[12]  
Johnson C.K., 1976, Oak Ridge National Laboratory Report ORNL, P5138
[13]  
LATAVALYA N, 1975, CRYST STRUCT COMMUN, V4, P163
[14]  
*MOL STRUCT CORP, 1989, TEXSAN VERS 1 11
[15]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&
[16]  
*RIG CORP, 1999, WIN AFC DIFFR CONTR
[17]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]
[18]   Preparation of Porous HAW/β-TCP Ceramics with In situ Synthesis of HA Whiskers [J].
Zan, Qingfeng ;
Han, Yaocong ;
Dong, Limin ;
Wang, Chen ;
Tian, Jiemo .
HIGH-PERFORMANCE CERAMICS VI, 2010, 434-435 :617-+