trans-bis(4-aminopyridine-κN)bis(succinimidato-κN)copper(II) dihydrate

被引:0
作者
Akitsu, T [1 ]
Einaga, Y [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词
D O I
10.1107/S1600536806006209
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu(C4H4NO2)(2)(C5H6N2)(2)]center dot 2H(2)O, has its metal atom in a square-planar trans-[CuN4] coordination environment; the Cu-II atom lies on a center of symmetry. Both succinimidate and 4-aminopyridine ligands behave as monodentate ligands, which coordinate through deprotonated imidate and pyridine ( not amino) N atoms, respectively. The 4-aminopyridine is the first ligand in such Cu-II complexes containing two different N atoms to take potentially different coordination modes.
引用
收藏
页码:M625 / M627
页数:3
相关论文
共 18 条
[1]   trans-Bis(2,2-diphenylethylaminexN)bis(5,5-diphenylhydantoinato- κN3)copper(II) and its chloroform disolvate [J].
Akitsu, T ;
Einaga, Y .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 :M183-M186
[2]   Thermal and photo-responsibility of axial semi-coordination bonds in a copper(II) complex [J].
Akitsu, T ;
Einaga, Y .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2004, 77 (04) :763-764
[3]   trans-bis(5,5-diphenylhydantoinato)bis(2-phenylethylamine)copper(II) [J].
Akitsu, T ;
Einaga, Y .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M524-M526
[4]   High axial coordination in a cis-coordinated succinimidatocopper(II) complex [J].
Akitsu, T ;
Komorita, S .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (04) :767-768
[5]   Assignment of d-d transitions of square planar [CuIIN4] complexes containing imidate and amine ligands by means of polarized crystal spectra. [J].
Akitsu, T ;
Komorita, S ;
Urushiyama, A .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2001, 74 (05) :851-860
[6]   Preparation and crystal structures of trans-bis(imidato)bis(1,2-diphenylethylamine)copper(II) complexes (imidato=5,5-diphenylhydantoinato and succinimidato).: Particular boundary cases of coordination geometry and monodentate ligand conformation [J].
Akitsu, T ;
Komorita, S ;
Kushi, Y .
INORGANICA CHIMICA ACTA, 2001, 315 (01) :18-25
[7]   Structures and Electronic Spectra of Aquadiiminebis(succinimidato)copper(II) Complexes with Square Pyramidal [CuN4O] Chromophores (Diimine=1,10-Phenanthroline and 2,2′-Bipyridine) [J].
Akitsu, Takashiro ;
Komorita, Seiko ;
Kushi, Yoshihiko .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (03) :447-454
[8]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[9]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[10]   Crystal engineering of NLO materials based on metal-organic coordination networks [J].
Evans, OR ;
Lin, WB .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522