Synthesis of diisopropylcyclopropenone and X-ray structure of its dichlorodimethyltin(IV) adduct

被引：0

作者：

Curnow, Owen J. ^{[1
]}

Fern, Glen M. ^{[1
]}

Pipal, Robert J. ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

ARKIVOC | 2006年

关键词：

crystal structure; cyclopropenone; tin complex;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diisopropylcyclopropenone was prepared by a dehydrobromination of 3,5-dibromo-2,6-dimethylheptan-4-one and isolated in 18% yield via an aqueous extraction procedure. It was characterised by an X-ray crystal structure analysis of its complex with dichlorodimethyltin(IV): Dichlorodimethyl(diisopropylcyclopropenone)tin(IV) was found to have a chloro-bridged dimeric structure in the solid state.

引用

页码：43 / 47

页数：5