Enhanced photoelectrochemical photocatalytic activities in hydrothermal synthesized SrTiO3/TiO2 heterostructure thin films

被引:6
作者
Khemakhem, Olfa [1 ,2 ,3 ]
Bennaceur, Jamila [2 ]
Cheikhrouhou-Koubaa, Wissem [1 ,3 ]
Koubaa, Mohamed [1 ]
Chtourou, Radhouane [2 ]
Cheikhrouhou, Abdelwaheb [1 ]
机构
[1] Sfax Univ, Fac Sci Sfax, Mat Phys Lab LPM, BP 1171, Sfax 3000, Tunisia
[2] Ctr Rech & Technol Energie, Lab Photovolta, Technopole Borj Cedria,BP 95, Hammamm Lif 2050, Tunisia
[3] Digital Res Ctr Sfax CRNS, Sfax Technopk,BP 275, Sakiet Ezzit 3021, Tunisia
关键词
Nanofibers; Hydrothermal method; Photocatalytic activity; TIO2 NANOWIRE ARRAYS; HYDROGEN-PRODUCTION; NANOTUBE ARRAYS; WATER; FABRICATION; EFFICIENCY; PERFORMANCE; ELECTRODE; ZNO;
D O I
10.1016/j.jallcom.2016.11.282
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Heterostructured SrTiO3/TiO2 nanofibers were fabricated, under various doping times, by two steps in situ hydrothermal method using TiO2 nanofibers as both template and reactant. The as-fabricated heterostructure composite included SrTiO3 nanocubes or nanoparticles assembled uniformly on the surface of TiO2 nanofibers undergoes a huge photoelectric performance, evaluated by the photo-to-dark current ratio, which reaches three orders of magnitude of that observed in TiO2. The results presented here can be owing to the improvement of charge separation derived from the coupling effect of TiO2 and SrTiO3 nanocomposites and demonstrate the potential prospects of heterostructures with smaller nanostructure size in fabricating high-response UV detectors. Furthermore, SrTiO3/TiO2 nanofibers exhibit enhanced photocatalytic activity in the decomposition of the methylene blue aqueous solution under ultraviolet light, which could be attributed to the improvement of charge separation derived from the coupling effect of TiO2 and SrTiO3 nanocomposites. (C) 2016 Elsevier B.V. All rights reserved. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:682 / 687
页数:6
相关论文
共 44 条
[1]   PHOTO-REDUCTION OF CARBON-DIOXIDE AND WATER INTO FORMALDEHYDE AND METHANOL ON SEMICONDUCTOR-MATERIALS [J].
AURIANBLAJENI, B ;
HALMANN, M ;
MANASSEN, J .
SOLAR ENERGY, 1980, 25 (02) :165-170
[2]   Hierarchical SrTiO3/TiO2 nanofibers heterostructures with high efficiency in photocatalytic H2 generation [J].
Bai, Hongwei ;
Juay, Jermyn ;
Liu, Zhaoyang ;
Song, Xiaoxiao ;
Lee, Siew Siang ;
Sun, Darren Delai .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 125 :367-374
[3]   Annealing effects on microstructural and optical properties of Nanostructured-TiO2 thin films prepared by solegel technique [J].
Ben Naceur, J. ;
Gaidi, M. ;
Bousbih, F. ;
Mechiakh, R. ;
Chtourou, R. .
CURRENT APPLIED PHYSICS, 2012, 12 (02) :422-428
[4]   PHOTOELECTROLYSIS AND PHYSICAL-PROPERTIES OF SEMICONDUCTING ELECTRODE WO3 [J].
BUTLER, MA .
JOURNAL OF APPLIED PHYSICS, 1977, 48 (05) :1914-1920
[5]   Fabrication of a novel heterostructure of Co3O4-modified TiO2 nanorod arrays and its enhanced photoelectrochemical property [J].
Cao, Chunlan ;
Hu, Chenguo ;
Shen, Weidong ;
Wang, Shuxia ;
Wang, Jianli ;
Tian, Yongshu .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 550 :137-143
[6]   A Facile in Situ Hydrothermal Method to SrTiO3/TiO2 Nanofiber Heterostructures with High Photocatalytic Activity [J].
Cao, Tieping ;
Li, Yuejun ;
Wang, Changhua ;
Shao, Changlu ;
Liu, Yichun .
LANGMUIR, 2011, 27 (06) :2946-2952
[7]   Nanocrystalline TiO2 photocatalytic membranes with a hierarchical mesoporous multilayer structure:: Synthesis, characterization, and multifunction [J].
Choi, Hyeok ;
Sofranko, Anna C. ;
Dionysiou, Dionysios D. .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (08) :1067-1074
[8]   ON THE MORPHOLOGICAL PROPERTIES OF TUNGSTA-TITANIA DE-NOXING CATALYSTS [J].
CRISTIANI, C ;
BELLOTTO, M ;
FORZATTI, P ;
BREGANI, F .
JOURNAL OF MATERIALS RESEARCH, 1993, 8 (08) :2019-2025
[9]   Axis-Oriented, Anatase TiO2 Single Crystals with Dominant {001} and {100} Facets [J].
Cuong Ky Nguyen ;
Cha, Hyun Gil ;
Kang, Young Soo .
CRYSTAL GROWTH & DESIGN, 2011, 11 (09) :3947-3953
[10]   Modified TiO2 For Environmental Photocatalytic Applications: A Review [J].
Daghrir, Rimeh ;
Drogui, Patrick ;
Robert, Didier .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (10) :3581-3599