3,3'-bis(3,4,5-trimethoxybenzoyl)-1,1'(o-phenylene)dithiourea ethanol solvate

被引:2
|
作者
Du, Hai-Tang [1 ]
Du, Hai-Jun [2 ]
机构
[1] Guiyang Coll, Ecoenvironm Sci Res Ctr, Inst Nat Prod, Guiyang 550005, Peoples R China
[2] Guizhou Univ Nationalities, Sch Chem & Environm Sci, Guiyang 550025, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808023556
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the molecule of the title compound, C28H30N4O8S2 center dot C2H6O, the benzene ring is oriented at dihedral angles of 38.50 (6) and 5.68 (5)degrees with respect to the trimethoxyphenyl rings, while the two trimethoxyphenyl rings are oriented at a dihedral angle of 44.18 (5)degrees. Intramolecular N-H center dot center dot center dot O and N-H center dot center dot center dot S hydrogen bonds result in the formation of non-planar six-, seven-and eight-membered rings. The twisting modes of the two side arms are different [C-N-C-O and C-N-C-N torsion angles = 0.1 (3) and 11.8 (3)degrees, respectively, in one arm, and 4.6 (3) and -11.5 (3)degrees in the other]. In the crystal structure, intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the molecules.
引用
收藏
页码:O1632 / U3497
页数:14
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