Application of reductive amination reaction for preparation of ferrocene-modified porphyrins

被引：14

作者：

Osipova, Elena Yu ^{[1
]}

Rodionov, Alexey N. ^{[1
]}

Simenel, Alexander A. ^{[1
,2
]}

Belousov, Yury A. ^{[1
]}

Nikitin, Oleg M. ^{[1
,3
]}

Kachala, Vadim V. ^{[4
]}

机构：

[1] AN Nesmeyanov Inst Organoelement Cpds RAS, Moscow 119991, Russia

[2] Moscow State Min Univ, Moscow 119991, Russia

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[4] ND Zelynski Inst Organ Chem RAS, Moscow 119991, Russia

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2012年 / 16卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

ferrocene; porphyrin; reductive amination; 5-(p-aminophenyl)-10,15,20-triphenylporphyrin; electrochemistry; PHOTODYNAMIC THERAPY; METAL-FREE; OXIDATION; POTENTIALS; DESIGN;

D O I：

10.1142/S1088424612501246

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porphyrin-modified ferrocenes were synthesized via the reductive amination reaction of ferrocenylpyrazolecarboxaldehydes and tetraphenylporphyrinamine. The steric hindrance of ferrocene moiety was found to play the key role in this reaction.

引用

页码：1225 / 1232

页数：8

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