Synthesis and Structure of Tetra- and Triphenylantimony Salicylaldoximates

被引：6

作者：

Sharutin, V. V. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Molokova, O. V. ^{[1
]}

机构：

[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 57卷 / 06期

关键词：

CRYSTAL; TETRAPHENYLANTIMONY; PENTAARYLANTIMONY; TRIORGANOANTIMONY;

D O I：

10.1134/S0036023612010226

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetraphenylantimony salicylaldoximate (I) was synthesized by reactions of pentaphenylantimony with salicylaldoxime or triphenylantimony disalicylaldoximate in toluene. Triphenylantimony bis(salicylaldoximate) (II) was synthesized by the reaction between triphenylantimony, hydrogen peroxide, and salicylaldoxime. The structures of compounds I and II were determined by X-ray crystallography. The coordination of Sb atoms in I and II is a distorted trigonal bipyramid. For compounds I and II, Sb-C bond lengths are 2.1132(13)-2.1760(14) angstrom and 2.1026(15)-2.112(2) angstrom, the Sb-O distances are 2.1771(11) angstrom and 2.0768(11) angstrom, and the Sb center dot center dot center dot N intermolecular contacts are equal to 2.945(2) angstrom and 2.882(2) angstrom, respectively.

引用

页码：832 / 837

页数：6

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