Green light emission by Ce3+ and Tb3+ co-doped Sr3MgSi2O8 phosphors for potential application in ultraviolet whitelight-emitting diodes

被引:41
作者
Yu, Hong [1 ]
Zi, Wenwen [1 ]
Lan, Shi [1 ]
Gan, Shucai [1 ]
Zou, Haifeng [1 ]
Xu, Xuechun [2 ]
Hong, Guangyan [3 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130026, Peoples R China
[2] Jilin Univ, Coll Earth Sci, Changchun 130026, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
关键词
Sr3MgSi2O8:Ce-3+; Ce-; Tb3+; Photoluminescence; ENERGY-TRANSFER; PHOTOLUMINESCENCE; LUMINESCENCE; SPECTRA; EU3+; RE;
D O I
10.1016/j.optlastec.2012.02.005
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Sr3MgSi2O8:Ce3+, Tb3+ phosphor samples were prepared using a solid-state reaction technique, and the photoluminescence properties and energy transfer were investigated. Effective energy transfer occurred in Ce3+/Tb3+ co-doped Sr3MgSi2O8 phosphors. Co-doping of Ce3+ was found to enhance the emission intensity of Tb3+ to a certain extent by transferring energy to Tb3+. The Ce3+/Tb3+ energy transfer was thoroughly investigated through its emission/excitation spectra and photoluminescence decay behavior. The color emitted by Sr3MgSi2O8:Ce3+, Tb3+ phosphors varied from blue to green and can be controlled by altering the concentration ratio of Ce3+ to Tb3+. These results indicate that Sr3MgSi2O8:Ce3+, Tb3+ may be useful as a green-emitting phosphor for ultraviolet whitelight-emitting diodes. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2306 / 2311
页数:6
相关论文
共 22 条
[11]   Versatile phosphors BaY2Si3O10:RE (RE = Ce3+, Tb3+, Eu3+) for light-emitting diodes [J].
Liu, Wei-Ren ;
Lin, Chun Che ;
Chiu, Yi-Chen ;
Yeh, Yao-Tsung ;
Jang, Shyue-Ming ;
Liu, Ru-Shi ;
Cheng, Bing-Ming .
OPTICS EXPRESS, 2009, 17 (20) :18103-18109
[12]   Photoluminescence and decay profiles of undoped and Fe3+, Eu3+-doped PLZT ceramics at low temperatures down to 10 K [J].
Murakami, S ;
Herren, M ;
Rau, D ;
Morita, M .
INORGANICA CHIMICA ACTA, 2000, 300 :1014-1021
[13]   INTENSITIES OF CRYSTAL SPECTRA OF RARE-EARTH IONS [J].
OFELT, GS .
JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (03) :511-&
[14]   Comparative investigation on synthesis and photoluminescence of YAG:Ce phosphor [J].
Pan, YX ;
Wu, MM ;
Su, Q .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 106 (03) :251-256
[15]   A promising red-emitting phosphor for white-light-emitting diodes prepared by a modified solid-state reaction [J].
Ren, Fuqiang ;
Chen, Donghua .
OPTICS AND LASER TECHNOLOGY, 2010, 42 (01) :110-114
[16]   REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].
SHANNON, RD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767
[17]   Luminescence studies on SrMgAl10O17:Eu, Dy phosphor crystals [J].
Tang Wanjun ;
Chen Donghua ;
Wu Ming .
OPTICS AND LASER TECHNOLOGY, 2009, 41 (01) :81-84
[18]   Investigation on Eu3+ doped Sr2MgSi2O7 red-emitting phosphors for white-light-emitting diodes [J].
Wu, Haoyi ;
Hu, Yihua ;
Wang, Yinhai ;
Kang, Fengwen ;
Mou, Zhongfei .
OPTICS AND LASER TECHNOLOGY, 2011, 43 (07) :1104-1110
[19]   Photoluminescence and energy transfer studies on Eu2+ and Ce3+ co-doped SrCaSiO4 for white light-emitting-diodes [J].
Yu, Hong ;
Lai, Yawen ;
Gao, Guimei ;
Kong, Li ;
Li, Guanghuan ;
Gan, Shucai ;
Hong, Guangyan .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (23) :6635-6639
[20]   Photoluminescence of double-color-emitting phosphor Ca5(PO4)3Cl:Eu2+, Mn2+ for near-UV LED [J].
Yu, Jie ;
Guo, Chongfeng ;
Ren, Zhaoyu ;
Bai, Jintao .
OPTICS AND LASER TECHNOLOGY, 2011, 43 (04) :762-766