Green light emission by Ce3+ and Tb3+ co-doped Sr3MgSi2O8 phosphors for potential application in ultraviolet whitelight-emitting diodes

被引:41
作者
Yu, Hong [1 ]
Zi, Wenwen [1 ]
Lan, Shi [1 ]
Gan, Shucai [1 ]
Zou, Haifeng [1 ]
Xu, Xuechun [2 ]
Hong, Guangyan [3 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130026, Peoples R China
[2] Jilin Univ, Coll Earth Sci, Changchun 130026, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
关键词
Sr3MgSi2O8:Ce-3+; Ce-; Tb3+; Photoluminescence; ENERGY-TRANSFER; PHOTOLUMINESCENCE; LUMINESCENCE; SPECTRA; EU3+; RE;
D O I
10.1016/j.optlastec.2012.02.005
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Sr3MgSi2O8:Ce3+, Tb3+ phosphor samples were prepared using a solid-state reaction technique, and the photoluminescence properties and energy transfer were investigated. Effective energy transfer occurred in Ce3+/Tb3+ co-doped Sr3MgSi2O8 phosphors. Co-doping of Ce3+ was found to enhance the emission intensity of Tb3+ to a certain extent by transferring energy to Tb3+. The Ce3+/Tb3+ energy transfer was thoroughly investigated through its emission/excitation spectra and photoluminescence decay behavior. The color emitted by Sr3MgSi2O8:Ce3+, Tb3+ phosphors varied from blue to green and can be controlled by altering the concentration ratio of Ce3+ to Tb3+. These results indicate that Sr3MgSi2O8:Ce3+, Tb3+ may be useful as a green-emitting phosphor for ultraviolet whitelight-emitting diodes. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2306 / 2311
页数:6
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