THE INFLUENCE OF POTENTIAL-CURRENT CONDITIONS ON THE ELECTRODEPOSITION OF Ni-Sn ALLOYS FROM ACIDIC CHLORIDE-SULPHATE SOLUTION

被引：6
作者：
Rudnik, E. [1 ]
Wloch, G. [2 ]
Czernecka, A. [1 ]
机构：
[1] AGH Univ Sci & Technol, Dept Phys Chem & Met Nonferrous Met, Fac Nonferrous Met, PL-30059 Krakow, Poland
[2] AGH Univ Sci & Technol, Dept Struct & Mech Solids, Fac Nonferrous Met, PL-30059 Krakow, Poland
来源：
ARCHIVES OF METALLURGY AND MATERIALS | 2014年 / 59卷 / 01期
关键词：
electrodeposition; nickel; tin; alloy; speciation; LITHIUM ION BATTERIES; NICKEL; DEPOSITION; COATINGS;
D O I：
10.2478/amm-2014-0031
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
Ni - Sn alloys were electrodeposited from acidic chloride-sulphate solution in potentiostatic and galvanostatic conditions. Cyclic voltammetry and Hull cell were used for the selection of the appropriate deposition potentials and cathodic current densities, respectively. In the potentiostatic conditions (-1.0 - -1.2 V vs. Ag/AgCl) porous deposits (similar to 7-10 wt% Ni) were obtained, while dense coatings(similar to 15-34 wt% Ni) were produced in the galvanostatic conditions (0.5-1.5 A/dm(2)). In both cases, deposits consisted of beta - Sn and Ni3Sn4 phases. Speciation of the bath was also calculated.
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页码：195 / 198
页数：4
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