Two new 3-D coordination polymers with 5-tert-butyl isophthalic acid and flexible N-donor co-ligands bearing linear trinuclear secondary building blocks

被引：23

作者：

Wang, Jian-Ge ^{[1
]}

Chai, Na ^{[1
]}

Wang, Sheng-Chun ^{[1
]}

Ma, Lu-Fang ^{[1
]}

Wang, Li-Ya ^{[1
,2
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

[2] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 30卷

基金：

中国国家自然科学基金;

关键词：

5-tert-Butyl isophthalic acid; 1,4-Bis(imidazol-1-yl)butane; 1,4-Bis(1,2,4-triazol-1-yl)butane; Magnetic properties; METAL-ORGANIC FRAMEWORKS; TOPOLOGICAL STRUCTURES; CRYSTAL-STRUCTURES; COMPLEXES; DICARBOXYLATE;

D O I：

10.1016/j.inoche.2013.02.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new 3-D coordination polymers bearing linear trinuclear secondary building blocks with mixed bridging ligands, {[Ni-3(tbip)(2)(Htbip)(2)(bib)(2)]center dot 4H(2)O}(n) (1) and {[Co-3(tbip)(2)(Htbip)(2)(btb)(2)]center dot 4H(2)O}(n). (2) (H(2)tbip = 5-tert-butyl isophthalic acid, bib = 1,4-bis(imidazol-1-yl)butane, btb = 1,4-bis(1,2,4-triazol-1-yl)butane), were obtained and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, single-crystal X-ray crystallography and powder X-ray diffraction. Both complexes 1 and 2 display similar 3D 6-connected pcu networks containing the linear trinuclear [M-3(COO)(6)] (M = Ni and Co) clusters as nodes. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：143 / 146

页数：4

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