Ionic-Liquid-Loaded β-Cyclodextrin-Cross-Linked Polymer Solid-Phase Extraction for the Separation/Analysis of Linuron in Fruit and Vegetable Samples

被引：11

作者：

Feng, Gang ^{[1
,2
]}

Ping, Wenhui ^{[1
]}

Qin, Xing Xiu ^{[1
]}

Liu, Jie ^{[1
]}

Zhu, Xiashi ^{[1
]}

机构：

[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou, Peoples R China

[2] Yangzhou Higher Commercial Vocat Sch, Yangzhou 225002, Peoples R China

来源：

FOOD ANALYTICAL METHODS | 2015年 / 8卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Linuron; IL-beta-CDCP; Solid-phase extraction; Inclusion interactions; Ultraviolet spectrophotometry; WASTE-WATER; CHROMATOGRAPHY; PESTICIDES; REMOVAL; CARBON;

D O I：

10.1007/s12161-015-0118-6

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

A novel method for the separation/analysis of linuron in fruit and vegetable samples is described. The work is based on the utilization of ionic liquid ([C(6)min][PF6])-loaded beta-cyclodextrin cross-linked polymer (IL-beta-CDCP) for the effective adsorption of linuron coupled with ultraviolet spectrophotometry. The inclusion interaction of IL-beta-CDCP with linuron is studied with FTIR and inclusion constants. Under optimum conditions, the preconcentration factor achieved for this method is approximately 10. Linear range, limit of detection (LOD), limit of quantification (LOQ), and relative standard deviation are 0.08-15.00 mu g/mL, 5.8 ng/mL, 17.5 ng/mL and 0.96%(n=3, c=4.0 mu g/mL), respectively. This technique is successfully applied for determination of linuron in real samples.

引用

页码：2315 / 2320

页数：6

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