Palladium-Catalyzed Carbonylation Reaction of Aryl Bromides with 2-Hydroxyacetophenones to Form Flavones

被引：47

作者：

Wu, Xiao-Feng ^{[1
,2
]}

Neumann, Helfried ^{[2
]}

Beller, Matthias ^{[2
]}

机构：

[1] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China

[2] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 40期

关键词：

aryl bromides; carbonylation; flavones; heterocycles; palladium; ONE-POT SYNTHESIS; COUPLING REACTIONS; O-IODOPHENOLS; HALIDES; AMINOCARBONYLATION; DERIVATIVES; ACETYLENES; ANNULATION; CHROMONES; CELLS;

D O I：

10.1002/chem.201202141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flavone of the month: A general and efficient method for the palladium-catalyzed carbonylative synthesis of flavones has been developed (see scheme). Starting from aryl bromides and 2-hydroxyacetophenones, the corresponding flavones have been isolated in good yields. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12595 / 12598

页数：4

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