A BODIPY based fluorescent chemosensor for Cu(II) ions and homocysteine/cysteine

被引：110
作者：
Li, Qian [1 ,2 ,3 ]
Guo, Yong [1 ,2 ]
Shao, Shijun [1 ,2 ]
机构：
[1] Chinese Acad Sci, Key Lab Chem NW Plant Resources, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Key Lab Nat Med Gansu Prov, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2012年 / 171卷
基金：
中国国家自然科学基金;
关键词：
BODIPY; Cations sensing; Cys/Hcy sensing; Fluorescent sensor; TURN-ON FLUORESCENT; AQUEOUS-SOLUTION; LIVING CELLS; SENSOR; DYES; CYSTEINE; PROBES; RECOGNITION; SELECTIVITY; ALZHEIMERS;
D O I：
10.1016/j.snb.2012.05.086
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A new BODIPY-based derivative 1 bearing phenolic OH groups was developed as a fluorescent sensor for Cu(II) ions and homocysteine/cysteine. Receptor 1 behaves as an "on-off" fluorescent sensor for the selective and sensitive detection of Cu(II) ions. The mechanism for the fluorescence response of receptor 1 toward Cu(II) ions could be explained by the widely accepted LMCT (ligand to metal charge transfer) process. The 1.Cu(II) could act as an efficient "off-on" fluorescent sensor for homocysteine/cysteine with high sensitivity. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：872 / 877
页数：6
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