Pseudo-2D Porous Networks via Interpenetration of 1D Zigzag Ladder-type Coordination Polymers: Adsorption and Separation of Xylene Isomers

被引：15

作者：

Lee, Soojin ^{[1
]}

Kim, Dongwon ^{[1
]}

Kim, Junhee ^{[1
]}

Jung, Ok-Sang ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Busan 46241, South Korea

来源：

CRYSTAL GROWTH & DESIGN | 2020年 / 20卷 / 06期

基金：

新加坡国家研究基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; SELECTIVITY; SORPTION; DESIGN; MOFS;

D O I：

10.1021/acs.cgd.0c00336

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of AgPF6 with a new C-3-symmetric tridentate N-donor ligand gives rise to unusual pseudo-2D porous networks with open channels via the interpenetration of 1D zigzag ladders. The open-channel networks selectively adsorb only m-xylene from the mixture of o- and m-xylene, with o-xylene thus acting as a channel-entrance stopper at room temperature. This system exemplifies unprecedented separation of o- and m-xylene.

引用

收藏

页码：3601 / 3604

页数：4

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