Construction of 1,5-Enynes by Stereospecific Pd-Catalyzed Allyl- Propargyi Cross-Couplings

被引：47
作者：
Ardolino, Michael J. [1 ]
Morken, James P. [1 ]
机构：
[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 21期
关键词：
ACID-PROMOTED CYCLIZATIONS; BOND-FORMING REACTIONS; NUCLEOPHILIC-SUBSTITUTION; REDUCTIVE ELIMINATION; ARYLBORONIC ACIDS; CONVENIENT METHOD; PALLADIUM; ALCOHOLS; COMPLEXES; ALLENES;
D O I：
10.1021/ja302329f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates.
引用
收藏
页码：8770 / 8773
页数：4
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