Synthesis and structure of an unprecedented supramolecular bridged-hydroxyl manganese(III)-lithium(I) coordination polymer [MnIIIL(OH)2LiI]n through both intermolecular hydrogen bonds and π-π stacking interactions

被引：45

作者：

Dong, Wen-Kui ^{[1
]}

Zhao, Chun-Yu ^{[1
]}

Sun, Yin-Xia ^{[1
]}

Tang, Xiao-Lu ^{[1
]}

He, Xue-Ni ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 03期

关键词：

Salen-type bisoxime ligand; Mn(III) polymer; Synthesis; Supramolecular structure; CRYSTAL-STRUCTURE; INFRARED-SPECTRA; COMPLEXES; EPOXIDATION;

D O I：

10.1016/j.inoche.2008.12.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unprecedented linear supramolecular manganese(III)-lithium(I) coordination polymer, [(MnL)-L-III(OH)(2)Li-I](n,) has been prepared and structurally characterized. The polymer is a one-dimensional infinite Mn(III)-O-Li(I) chain supramolecular structure formed by intermolecular O-H-center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds and pi-pi stacking of neighboring benzene rings. (C) 2009 Published by Elsevier B.V.

引用

页码：234 / 236

页数：3