Control of pore and window size of ceramic foams with tri-modal pore structure: Influence of agar concentration

被引:16
作者
Han, Yosep [1 ]
Choi, Junhyun [1 ]
Kim, Hyung-Seok [2 ]
Kim, Hyunjung [1 ]
Park, Jayhyun [3 ]
机构
[1] Chonbuk Natl Univ, Dept Mineral Resource & Energy Engn, Jeonju 561756, Jeonbuk, South Korea
[2] Korea Inst Geosci & Mineral Resources, Mineral Resources Res Div, Taejon 305350, South Korea
[3] Inst Mine Reclamat Corp, Coal Ctr, R&D Team, Seoul 110727, South Korea
基金
新加坡国家研究基金会;
关键词
Ceramic foams; Agar gelation; Tri-modal pore structure; Physical properties; Microstructure; POROUS CERAMICS; MONOLITHS; SILICA;
D O I
10.1016/j.matlet.2013.05.100
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The present study relates to manufacturing of highly porous ceramics having a hierarchical tri-modal pore structure via foaming and agar gelation. Formations of macropores caused by foaming, window pores that pores are connected each other, and micropores caused by agar were confirmed through the present study. The amount of agar addition significantly influenced the theological behavior of slurry, which consequently affected physical properties of final products. Though total, open, and closed porosity was not sensitive to agar contents added, microporosity and specific surface area increased and average pore and window (i.e., a pore generated by contact of macropores) size decreased with increasing agar contents, respectively. Additionally, ceramic foams prepared with higher agar contents exhibited more uniform pore size (i.e., lower uniformity factor). Gelation rate, which was sensitive to the amount of agar and controlling bubble stabilization rate, was found to be a critical factor affecting physical properties of ceramic foams. The results suggest that the control of pore structure of ceramic foams is feasible by adjusting the level of agar contents. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:256 / 259
页数:4
相关论文
共 20 条
[1]   Gelcasting of alumina and zirconia using chitosan gels [J].
Bengisu, M ;
Yilmaz, E .
CERAMICS INTERNATIONAL, 2002, 28 (04) :431-438
[2]   Processing of hydroxyapatite ceramic foams [J].
Binner, JGP ;
Reichert, J .
JOURNAL OF MATERIALS SCIENCE, 1996, 31 (21) :5717-5723
[3]   In praise of pores [J].
Colombo, Paolo .
SCIENCE, 2008, 322 (5900) :381-383
[4]   Microstructure and properties of LZSA glass-ceramic foams [J].
de Sousa, E. ;
Rambo, C. R. ;
Hotza, D. ;
de Oliveira, A. P. Novaes ;
Fey, T. ;
Greil, P. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 476 (1-2) :89-97
[5]   Modification of porous silica with activated carbon and its application for fixation of yeasts [J].
Furuta, S ;
Katsuki, H ;
Komarneni, S .
JOURNAL OF POROUS MATERIALS, 2001, 8 (01) :43-48
[6]   Millimeter-sized spherical ion-sieve foams with hierarchical pore structure for recovery of lithium from seawater [J].
Han, Yosep ;
Kim, Hyunjung ;
Park, Jaikoo .
CHEMICAL ENGINEERING JOURNAL, 2012, 210 :482-489
[7]   Preparation of Sizable and Uniform-Sized Spherical Ceramic Foams: Drop-in-Oil and Agar Gelation [J].
Han, Yosep ;
Kim, Seongmin ;
Kim, Hyunjung ;
Park, Jaikoo .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (09) :2742-2745
[8]   Fabrication and characterization of macroporous flyash ceramic pellets [J].
Han, Yosep ;
Kim, Hyunjung ;
Park, Jaikoo .
MATERIALS CHARACTERIZATION, 2011, 62 (09) :817-824
[9]   Nanosized mesoporous silica coatings on ceramic foams:: New hierarchical rigid monoliths [J].
Huerta, Lenin ;
El Haskouri, Jamal ;
Vie, David ;
Comes, Maria ;
Latorre, Julio ;
Guillem, Carmen ;
Marcos, M. Dolores ;
Martinez-Manez, Ramom ;
Beltran, Aurelio ;
Beltran, Daniel ;
Amoros, Pedro .
CHEMISTRY OF MATERIALS, 2007, 19 (05) :1082-1088
[10]   Evaluation of permeable pore sizes of macroporous materials using a modified gas permeation method [J].
Kim, Hyunjung ;
Han, Yoseop ;
Park, Jaikoo .
MATERIALS CHARACTERIZATION, 2009, 60 (01) :14-20