The diverted Di-π-methane rearrangement;: mechanistic and exploratory organic photochemistry

被引：7

作者：

Zimmerman, HE ^{[1
]}

Chen, WS ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 07期

关键词：

D O I：

10.1021/ol025564h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] An unusual diversion of the di-pi-methane rearrangement has been encountered. The reaction is characteristic of di-pi-methane systems having one vinyl group bearing one or two carbonyl groups and provides a synthesis of dihydrofurans.

引用

页码：1155 / 1158

页数：4

共 7 条

[1]

Frisch M.J., 1998, GAUSSIAN 98

[2]

Zimmerman HE, 2001, HELV CHIM ACTA, V84, P1342, DOI 10.1002/1522-2675(20010613)84:6<1342::AID-HLCA1342>3.0.CO

[3]

2-W

[4] PHOTOCHEMICAL SERIES .126. DI-PI-METHANE HYPERSURFACES AND REACTIVITY - MULTIPLICITY AND REGIOSELECTIVITY - RELATIONSHIP BETWEEN THE DI-PI-METHANE AND BICYCLE REARRANGEMENTS MECHANISTIC AND EXPLORATORY ORGANIC-PHOTOCHEMISTRY [J].

ZIMMERMAN, HE ;

FACTOR, RE .

TETRAHEDRON, 1981, 37 :125-141

[5] PHOTO-CHEMICAL SERIES .120. UNUSUAL ORGANIC-PHOTOCHEMISTRY EFFECTED BY CYANO AND METHOXY SUBSTITUTION - EXPLORATORY AND MECHANISTIC ORGANIC-PHOTOCHEMISTRY [J].

ZIMMERMAN, HE ;

ARMESTO, D ;

AMEZUA, MG ;

GANNETT, TP ;

JOHNSON, RP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (21) :6367-6383

[6] Excited- and ground-state versions of the tri-π-methane rearrangement:: Mechanistic and exploratory organic photochemistry [J].

Zimmerman, HE ;

Církva, V .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (05) :1839-1851

[7] Synthetic aspects of the di-pi-methane rearrangement [J].

Zimmerman, HE ;

Armesto, D .

CHEMICAL REVIEWS, 1996, 96 (08) :3065-3112

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