A Fluorescent Ratiometric Chemodosimeter for Cu2+ Based on TBET and Its Application in Living Cells

被引:161
作者
Fan, Jiangli [1 ]
Zhan, Peng [1 ]
Hu, Mingming [1 ]
Sun, Wen [1 ]
Tang, Jizhou [1 ]
Wang, Jingyun [1 ]
Sun, Shiguo [1 ]
Song, Fengling [1 ]
Peng, Xiaojun [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
基金
国家高技术研究发展计划(863计划);
关键词
ENERGY-TRANSFER; HG2+; CASSETTES; COPPER; IONS;
D O I
10.1021/ol3032889
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Based on a through bond energy transfer (TBET) between Rhodamlne and a naphthalimide fluorophore, a fluorescent ratiometric chemodosimeter AM was designed and prepared for single selective detection of Cu2+ in aqueous solution and in living cells, as Cu2+ acts as not only a selective recognizing guest but also a hydrolytic promoter.
引用
收藏
页码:492 / 495
页数:4
相关论文
共 24 条
[1]   Copper-induced modifications of the trophic relations in riverine algal-bacterial biofilms [J].
Barranguet, C ;
van den Ende, FP ;
Rutgers, M ;
Breure, AM ;
Greijdanus, M ;
Sinke, JJ ;
Admiraal, W .
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 2003, 22 (06) :1340-1349
[2]   New Fluorogenic Sensors for Hg2+ Ions: Through-Bond Energy Transfer from Pentaquinone to Rhodamine [J].
Bhalla, Vandana ;
Roopa ;
Kumar, Manoj ;
Sharma, Parduman Raj ;
Kaur, Tandeep .
INORGANIC CHEMISTRY, 2012, 51 (04) :2150-2156
[3]   Fluorescent indicators based on BODIPY [J].
Boens, Noel ;
Leen, Volker ;
Dehaen, Wim .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (03) :1130-1172
[4]   A long-wavelength fluorescent chemodosimeter selective for Cu(II) ion in water [J].
Dujols, V ;
Ford, F ;
Czarnik, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (31) :7386-7387
[5]   Energy transfer cassettes based on organic fluorophores: construction and applications in ratiometric sensing [J].
Fan, Jiangli ;
Hu, Mingming ;
Zhan, Peng ;
Peng, Xiaojun .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (01) :29-43
[6]   A new rhodamine-based chemosensor for Cu2+ and the study of its behaviour in living cells [J].
Huang, Liang ;
Wang, Xiao ;
Xie, Guoqiang ;
Xi, Pinxian ;
Li, Zhengpeng ;
Xu, Min ;
Wu, Yongjie ;
Bai, Decheng ;
Zeng, Zhengzhi .
DALTON TRANSACTIONS, 2010, 39 (34) :7894-7896
[7]  
Krämer R, 1998, ANGEW CHEM INT EDIT, V37, P772, DOI 10.1002/(SICI)1521-3773(19980403)37:6<772::AID-ANIE772>3.0.CO
[8]  
2-Z
[9]   Naphthalimide Appended Rhodamine Derivative: Through Bond Energy Transfer for Sensing of Hg2+ Ions [J].
Kumar, Manoj ;
Kumar, Naresh ;
Bhalla, Vandana ;
Singh, Hardev ;
Sharma, Parduman Raj ;
Kaur, Tandeep .
ORGANIC LETTERS, 2011, 13 (06) :1422-1425
[10]   A kinetic study on the distribution of Cu(II)-ions between albumin and transferrin [J].
Lovstad, RA .
BIOMETALS, 2004, 17 (02) :111-113