Unique self-catenated 3D Cd(II)-MOF with a rare (3,3,9)-connected underlying network exhibiting high photocatalytic activities

被引：18

作者：

Kang, Wen-Chao ^{[1
]}

Liu, Dong ^{[1
]}

Blatov, Vladislav A. ^{[2
]}

Cui, Guang-Hua ^{[1
]}

机构：

[1] North China Univ Sci & Technol, Coll Chem Engn, Hebei Key Lab Environm Photocatalyt & Electrocata, 21 Bohai Rd, Tangshan 063210, Hebei, Peoples R China

[2] Samara State Tech Univ, SCTMS, Molodogvardeyskaya St 244, Samara 443100, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2019年 / 102卷

基金：

中国国家自然科学基金; 俄罗斯基础研究基金会;

关键词：

Crystal structure; Metal-organic framework; Photocatalytic activities; Self-catenated; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; MOF; DEGRADATION;

D O I：

10.1016/j.inoche.2019.02.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unprecedented 3D self-catenated topology with highly connected metal-organic framework, [Cd-3(nbta)(1.5)(btb)(2)(H2O)](n). (1) (H(3)nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, btb = 4,4'-bis(1,2,4-triazol-1-yl)-biphenyl) on the basis of Cd3 clusters was hydrothermally synthesized and characterized. Compound 1 possesses a unique (3,3,9)-coordinated framework, in which the nbta(3-) ligands serve as two unusual penta-dentate and heptadentate coordination modes. Compound 1 exhibits highly photocatalytic activities for the degradation of MB/MO/RhB organic dyes.

引用

页码：126 / 129

页数：4

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