Synthesis, Characterization, and Catalytic Activity of Metallo Octamethylcalix (4) Pyridino Complexes Encapsulated in MCM-41

被引：4

作者：

Rohitha, C. N. ^{[1
]}

Kulkarni, S. J. ^{[1
]}

Narender, N. ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Catalysis Grp, Hyderabad 500607, Andhra Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 21期

关键词：

Encapsulation; MCM-41; metallomacrocycles; molecular sieves; oxidation; SCHIFF-BASE COMPLEXES; ZEOLITE; OXIDATION; DIOXYGEN; PHTHALOCYANINE; PORPHYRIN; COBALT;

D O I：

10.1080/00397911.2012.745565

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and encapsulation of M+n-octamethylcalix(4)pyridino complexes using acetone and pyridine in H-MCM-41 have been achieved and presented. These hybrid catalysts are characterized by x-ray diffraction, infrared, thermal analysis, Brunauer-Emmett-Teller (BET) surface area, and scanning electron microscopy and tested for catalytic activity. They are active in the liquid-phase oxidation of p-xylene using H2O2 as oxidant and acetic acid as solvent in the temperature range of 30-100 degrees C. The variation of central transition-metal cation and the heterocyclic ring in the metallomacrocycle influence the catalytic activity. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]

引用

页码：2853 / 2866

页数：14