Phase-dependent ionization of Rydberg atoms in static fields

Using a laser intensity modulated synchronously with a 15.9 GHz microwave field we have examined laser excitation of Li atoms to the vicinity of the ionization limit in the presence of the microwave field and a parallel static field. The static field breaks the symmetry of ionization in the two microwave half cycles, and as the intensity modulated laser beam is delayed relative to the microwave field, maxima in the ionization are observed every microwave field cycle, not every half cycle, as in the absence of the static field. When the laser is tuned below the ionization limit there is an unexpected phase reversal of the modulation in the ionization, the origin of which is clarified by a classical model.