Synthesis and electronic properties of donor-acceptor π-conjugated siloles

被引：83

作者：

Boydston, AJ ^{[1
]}

Yin, Y ^{[1
]}

Pagenkopf, BL ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 12期

关键词：

D O I：

10.1021/ja049758z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient method is presented for the synthesis of novel donor?acceptor silole chromophores through selective monohalogenation of 2,5-dimetallosiloles followed by Negishi alkyne cross-coupling reactions. The electronic properties and crystal packing of these new siloles can be controlled through judicious combinations of peripheral functional groups. Copyright © 2004 American Chemical Society.

引用

页码：3724 / 3725

页数：2

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