Synthesis, X-ray structural and magnetic characterizations, and epoxidation activity of a new bis(μ-acetato)(μ-alkoxo)dinuclear iron(III) complex

被引：28

作者：

Biswas, Bhaskar ^{[1
]}

Mitra, Merry ^{[1
]}

Adhikary, Jaydeep ^{[2
]}

Krishna, G. Rama ^{[3
]}

Bag, Partha Pratim ^{[3
]}

Reddy, C. Malla ^{[3
]}

Aliaga-Alcalde, Nuria ^{[4
,5
]}

Chattopadhyay, Tanmay ^{[6
]}

Das, Debasis ^{[2
]}

Ghosh, Rajarshi ^{[1
]}

机构：

[1] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India

[2] Univ Calcutta, Univ Coll Sci & Technol, Dept Chem, Kolkata 700009, India

[3] Indian Inst Sci Educ & Res, Dept Chem Sci, Kolkata 741252, India

[4] Univ Barcelona, ICREA, E-08028 Barcelona, Spain

[5] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[6] Panchakot Mahavidyalaya, Dept Chem, Purulia 723121, India

来源：

POLYHEDRON | 2013年 / 53卷

关键词：

Iron(III); Schiff base; Crystal structure; Magnetism; Epoxidation; CATALYZED OXIDATION REACTIONS; DINUCLEAR; ALCOHOLS; LIGAND; OXYGENATION; SELECTIVITY; NICKEL(II); POLYMER; ALKENES; OLEFINS;

D O I：

10.1016/j.poly.2012.12.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, crystal structure and variable temperature magnetic measurements of a new dinuclear Fe(III) complex, [Fe-2(mu(1,3)-O(2)Cfn)(OH2)(MeOH)Cl2L] (1) [fn = furan, L = N,N'-bis(salicyaldehydene)-1,3-diaminopropan-2-ol], is reported. From X-ray diffractometry, it is shown that each Fe(III) centre in I is in a distorted octahedral environment. A variable temperature magnetic study reveals strong antiferromagnetic behaviour of 1 with J = -22.2 +/- 0.1 cm(-1). Use of 1 as an alkene epoxidation catalyst towards (E)-stilbene and styrene with tert-butyl hydrogen peroxide (TBHP) and iodosylbenzene (PhIO) reveals that TBHP is the better oxidant in terms of the yield of the reaction. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：264 / 268

页数：5

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