The effect of antimony-doping on Ge2Sb2Te5, a phase change material

被引:40
作者
Choi, Kyu-Jeong [1 ]
Yoon, Sung-Min [1 ]
Lee, Nam-Yeal [1 ]
Lee, Seung-Yun [1 ]
Park, Young-Sam [1 ]
Yu, Byoung-Gon [1 ]
Ryu, Sang-Ouk [2 ]
机构
[1] ETRI, IT Convergence & Components Lab, Taejon 305700, South Korea
[2] Dankook Univ, Dept Elect Engn, Chungnam 330714, South Korea
关键词
Phase change memory; Phase transition; Ge2Sb2Te5; excess-Sb Ge2Sb2+xTe5;
D O I
10.1016/j.tsf.2008.02.014
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The structural and electrical resistance properties of excess-Sb Ge2Sb2+xTe5 (Sb-GST) films were investigated. As the Sb-doping concentration was increased, the face center cubic structure of Sb-GST films was no longer observed, at Sb concentrations exceeding 27%, the amorphous phase directly changed to hexagonal closed-packed structures. The crystallization temperature of the 27% Sb-GST film was 15 degrees C higher than that of the Ge2Sb2Te5 (GST) film. The activation energies of the Sb-GST films also were greater than those of the GST films. These results indicate an increase in the stability of the Sb-doped films in the amorphous state compared with GST films. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:8810 / 8812
页数:3
相关论文
共 14 条
  • [1] Structural transformations of Ge2Sb2Te5 films studied by electrical resistance measurements
    Friedrich, I
    Weidenhof, V
    Njoroge, W
    Franz, P
    Wuttig, M
    [J]. JOURNAL OF APPLIED PHYSICS, 2000, 87 (09) : 4130 - 4134
  • [2] KISSINGER HE, 1957, ANAL CHEM, V29, P1702, DOI DOI 10.1021/AC60131A045
  • [3] Understanding the phase-change mechanism of rewritable optical media
    Kolobov, AV
    Fons, P
    Frenkel, AI
    Ankudinov, AL
    Tominaga, J
    Uruga, T
    [J]. NATURE MATERIALS, 2004, 3 (10) : 703 - 708
  • [4] MATSUI Y, 2006, INT EL DEV M
  • [5] Single structure widely distributed in a GeTe-Sb2Te3 pseudobinary system:: A rock salt structure is retained by intrinsically containing an enormous number of vacancies within its crystal
    Matsunaga, T
    Kojima, R
    Yamada, N
    Kifune, K
    Kubota, Y
    Tabata, Y
    Takata, M
    [J]. INORGANIC CHEMISTRY, 2006, 45 (05) : 2235 - 2241
  • [6] Structural, electric and kinetic parameters of ternary alloys of GeSbTe
    Morales-Sánchez, E
    Prokhorov, EF
    González-Hernández, J
    Mendoza-Galván, A
    [J]. THIN SOLID FILMS, 2005, 471 (1-2) : 243 - 247
  • [7] Oh J H, 2006, INT EL DEV M, P26
  • [8] Phase-change behavior of stoichiometric Ge2Sb2Te5 in phase-change random access memory
    Park, Jong-Bong
    Park, Gyeong-Su
    Baik, Hion-Suck
    Lee, Jang-Ho
    Jeong, Hongsik
    Kim, Kinam
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (03) : H139 - H141
  • [9] PELLIZZER F, 2006, S VLSI TECHN
  • [10] Crystallization behavior and physical properties of Sb-excess Ge2Sb2+xTe5 thin films for phase change memory (PCM) devices
    Ryu, SO
    Yoon, SM
    Choi, KJ
    Lee, NY
    Park, YS
    Lee, SY
    Yu, BG
    Park, JB
    Shin, WC
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (03) : G234 - G237