Synthesis, Characterization, and Antibacterial Studies of Some Metal Complexes of Dialkyl Thiourea: The X-Ray Single Crystal Structure of [CoCl2(detu)2]

被引：10

作者：

Ajibade, Peter A. ^{[1
]}

Zulu, Nonkululeko H. ^{[1
]}

Oyedeji, Adebola O. ^{[2
]}

机构：

[1] Univ Ft Hare, Dept Chem, ZA-5700 Alice, South Africa

[2] Walter Sisulu Univ, Dept Chem & Chem Technol, Mthatha, South Africa

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 05期

基金：

新加坡国家研究基金会;

关键词：

antibacterial; characterization; crystal structure; dialkyl thiourea; metal complexes; NN-DISUBSTITUTED THIOUREAS; IN-VITRO ANTIPROTOZOAL; CHEMISTRY; THERAPY;

D O I：

10.1080/15533174.2012.741179

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Co(II), Cu(II), and Zn(II) complexes of diethylthiourea and dimethylthiourea have been synthesized and characterized by elemental analysis, conductivity, magnetic susceptibility measurements, and FTIR UV-vis spectroscopy. The single-crystal X-ray structure of the Co(II) complex of diethylthiourea, [CoCl2(detu)2], is reported. The metal(II) complexes are four coordinated with two molecules of the alkyl thiourea and two molecules of either chloride or acetate ions. The compounds are nonelectrolytes in solution and the spectroscopic analysis is consistent with the proposed structures. The complexes were screened against six bacteria isolates to determine their antibacterial potentials.

引用

页码：524 / 531

页数：8

共 51 条

[1] X-ray crystal structure and infrared spectrum of the monoclinic form of dichlorobis(N,N′-diethylthiourea)cobalt(II) [J].

Abbati, GL ;

Aragoni, MC ;

Arca, M ;

Isaia, F ;

Lippolis, V .

JOURNAL OF COORDINATION CHEMISTRY, 1999, 47 (01) :91-97

[2] Spectroscopic characterization of some tetradentate Schiff bases and their complexes with nickel, copper and zinc [J].

Abd-Elzaher, MM .

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2001, 48 (02) :153-158

[3] Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes [J].

Abdul-Ghani, Ahlam J. ;

Khaleel, Asmaa M. N. .

BIOINORGANIC CHEMISTRY AND APPLICATIONS, 2009, 2009

[4] METAL-COMPOUNDS IN THERAPY AND DIAGNOSIS [J].

ABRAMS, MJ ;

MURRER, BA .

SCIENCE, 1993, 261 (5122) :725-730

[5]

Ajibade P.A., 2010, SYNTH REACT MET ORG, V40, P275

[6]

Ajibade P.A., 2008, B CHEM SOC ETHIOPIA, V22, P1

[7] Synthesis, characterization and in vitro antiprotozoal studies of iron(III) complexes of some antimalarial drugs [J].

Ajibade, Peter A. ;

Kolawole, Gabriel A. .

JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (21) :3367-3374

[8] Synthesis, characterization and antiprotozoal studies of some metal complexes of antimalarial drugs [J].

Ajibade, Peter A. ;

Kolawole, Gabriel A. .

TRANSITION METAL CHEMISTRY, 2008, 33 (04) :493-497

[9] Metal complexes of 4-amino-N-(2-pyrimidinyl)benzene sulfonamide: Synthesis, characterization and Antiprotozoal studies [J].

Ajibade, Peter A. ;

Kolawole, Gabriel A. ;

O'Brien, Paul .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2007, 37 (08) :653-659

[10] Metal Complexes of Diisopropylthiourea: Synthesis, Characterization and Antibacterial Studies [J].

Ajibade, Peter A. ;

Zulu, Nonkululeko H. .

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2011, 12 (10) :7186-7198

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