Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride

被引：135

作者：

Bahrami, K ^{[1
]}

机构：

[1] Razi Univ, Dept Chem, Kermanshah 67149, Iran

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 12期

关键词：

D O I：

10.1016/j.tetlet.2006.01.051

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride is a very efficient reagent for the oxidation of sulfides to sulfoxides and sulfones in methanol at room temperature. It is noteworthy that under such conditions, the sulfide function is highly reactive, and various other functional groups such as alkenes and a ketone are tolerated. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：2009 / 2012

页数：4

共 29 条

[1] Selective and mild oxidation of sulfides to sulfoxides by oxodiperoxo molybdenum complexes adsorbed onto silica gel
Batigalhia, F
Zaldini-Hernandes, M
Ferreira, AG
Malvestiti, I
Cass, QB
[J]. TETRAHEDRON, 2001, 57 (48) : 9669 - 9676
[2] Oxidation of organic sulfides by Br2 and H2O2.: Electrophilic and free-radical processes
Bravo, A
Dordi, B
Fontana, F
Minisci, F
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (09) : 3232 - 3234
[3] Chemoselective and efficient oxidation of sulfides to sulfoxides mediated by trimethylsilyl chloride and superoxide via a trimethylsilylperoxy radical
Chen, YJ
Huang, YP
[J]. TETRAHEDRON LETTERS, 2000, 41 (27) : 5233 - 5236
[4] Tungstate-exchanged Mg-Al-LDH catalyst: an eco-compatible route for the oxidation of sulfides in aqueous medium
Choudary, BM
Bharathi, B
Reddy, CV
Kantam, ML
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2002, (18): : 2069 - 2074
[5] Clark E., 1997, KIRK OTHMER ENCY CHE, V23, P134
[6] CONVERSION OF SULFIDES TO THEIR CORRESPONDING SULFOXIDES WITH BARIUM PERMANGANATE BA(MNO4)2 UNDER NONAQUEOUS CONDITION
FIROUZABADI, H
SEDDIGHI, M
[J]. SYNTHETIC COMMUNICATIONS, 1991, 21 (02) : 211 - 214
[7] ZINC BISMUTHATE ZN(BIO3)2 .1. A USEFUL OXIDIZING-AGENT FOR THE EFFICIENT OXIDATION OF ORGANIC-COMPOUNDS
FIROUZABADI, H
MOHAMMADPOURBALTORK, I
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (04) : 1131 - 1134
[8] GREENHALGH RP, 1992, SYNLETT, P235
[9] Selective and efficient oxidation of sulfides and thiols with benzyltriphenylphosphonium peroxymonosulfate in aprotic solvent
Hajipour, AR
Mallakpour, SE
Adibi, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (24) : 8666 - 8668
[10] HOLLINGWORTH GJ, 1995, COMPREHENSIVE ORGANI, V2, P144

← 1 2 3 →