Electrochemical deposition of aniline derivatives for conductometric gas sensors

被引:7
作者
Mateos, M. [1 ]
Prest, R. Meunier [1 ]
Suisse, J. M. [1 ]
Bouvet, M. [1 ]
机构
[1] Univ Bourgogne Franche Comte, Univ Bourgogne, Inst Chim Mol, CNRS,UMR 6302, F-21078 Dijon, France
关键词
ammonia; heterojunction; conductometric sensors; polytetrafluoroaniline;
D O I
10.1016/j.matpr.2018.10.426
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polymer films of poly(2,3,5,6-tetrafluoroaniline) (PTFA) were electroplated on ITO substrates from an acidic solution of the monomer by chronoamperometry. Electrochemical and morphological characterizations were performed and compared to these of polyaniline. The PTFA film presents a poor conductivity due to the absence of acid-base doping and a quasi irreversible redox response. This film was then incorporated in a patented device called MSDI heterojunction to perform ammonia sensing in humid atmosphere. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:328 / 332
页数:5
相关论文
共 8 条
[1]   Characterization and electrochromic properties of poly(2,3,5,6-tetrafluoroaniline): Progress towards a transparent conducting polymer [J].
Astratine, Lavinia ;
Magner, Edmond ;
Cassidy, John ;
Betts, Anthony .
ELECTROCHIMICA ACTA, 2012, 74 :117-122
[2]  
CLARISSE C, 1987, INORG CHIM ACTA, V130, P139
[3]   Bias and humidity effects on the ammonia sensing of perylene derivative/lutetium bisphthalocyanine MSDI heterojunctions [J].
Gaudillat, Pierre ;
Wannebroucq, Amelie ;
Suisse, Jean-Moise ;
Bouvet, Marcel .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 222 :910-917
[4]  
MacDiarmid AG, 2001, ANGEW CHEM INT EDIT, V40, P2581, DOI 10.1002/1521-3773(20010716)40:14<2581::AID-ANIE2581>3.0.CO
[5]  
2-2
[6]   Polyaniline as a new sensitive layer for gas sensors [J].
Nicolas-Debarnot, D ;
Poncin-Epaillard, F .
ANALYTICA CHIMICA ACTA, 2003, 475 (1-2) :1-15
[7]   Molecular semiconductor-doped insulator (MSDI) heterojunctions: an alternative transducer for gas chemosensing [J].
Parra, Vicente ;
Brunet, Jerome ;
Pauly, Alain ;
Bouvet, Marcel .
ANALYST, 2009, 134 (09) :1776-1778
[8]   Synthesis and characterization of fluoro-substituted polyaniline [J].
Sharma, AL ;
Gerard, M ;
Singhal, R ;
Malhotra, BD ;
Annapoorni, S .
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 2001, 96 (1-3) :155-165