Tunable white luminescence and energy transfer in (Cu+)2, Eu3+ codoped sodium silicate glasses

被引:110
作者
Guo, Hai [1 ]
Wei, RongFei [1 ]
Liu, XueYun [1 ]
机构
[1] Zhejiang Normal Univ, Dept Phys, Jinhua 321004, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
DOPED OXYFLUORIDE GLASSES; LIGHT-EMITTING-DIODES; ULTRAVIOLET-LIGHT; PHOSPHORS; CU+; CONVERSION; EMISSION; CE3+; ION; AG;
D O I
10.1364/OL.37.001670
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Luminescent properties of (Cu+)(2), Eu3+ single-doped and codoped sodium silicate glasses were systematically investigated by excitation spectra, emission spectra, and decay curves. Due to the efficient energy transfer from (Cu+)(2) pairs to Eu3+, varied hues from green to yellowish white and eventually to orange were generated by tuning the content of Eu3+. A perfect white-light emission with CIE coordinates (X = 0.336; Y = 0.346) was realized in (Cu+)(2), Eu3+ and Ce3+ codoped samples. Our research indicates the potential application of (Cu+)(2), Eu3+ codoped sodium silicate glasses for converting phosphors for UV LED chips to generate white LEDs. (C) 2012 Optical Society of America
引用
收藏
页码:1670 / 1672
页数:3
相关论文
共 18 条
[1]   OPTICAL SPECTROSCOPY OF COPPER(I)-DOPED NA+-BETA''-ALUMINA [J].
BARRIE, JD ;
DUNN, B ;
HOLLINGSWORTH, G ;
ZINK, JI .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (10) :3958-3963
[2]   FLUORESCENCE PROPERTIES OF CU+ ION IN PHOSPHATE-GLASSES OF THE BALIPO4-P2O5 SYSTEM [J].
BOUTINAUD, P ;
DULOISY, E ;
PEDRINI, C ;
MOINE, B ;
PARENT, C ;
LEFLEM, G .
JOURNAL OF SOLID STATE CHEMISTRY, 1991, 94 (02) :236-243
[3]   CeF3-based glass ceramic: a potential luminescent host for white-light-emitting diode [J].
Chen, Daqin ;
Yu, Yunlong ;
Lin, Hang ;
Huang, Ping ;
Weng, Fangyi ;
Shan, Zhifa ;
Wang, Yuansheng .
OPTICS LETTERS, 2009, 34 (19) :2882-2884
[4]   Efficient red-emitting phosphor for near-ultraviolet-based solid-state lighting [J].
Deng, Kaimo ;
Gong, Tao ;
Chen, Yonghu ;
Duan, Changkui ;
Yin, Min .
OPTICS LETTERS, 2011, 36 (23) :4470-4472
[5]   Plasmonic Enhancement or Energy Transfer? On the Luminescence of Gold-, Silver-, and Lanthanide-Doped Silicate Glasses and Its Potential for Light-Emitting Devices [J].
Eichelbaum, Maik ;
Rademann, Klaus .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (13) :2045-2052
[6]   Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation [J].
Fukumi, K ;
Chayahara, A ;
Ohora, K ;
Kitamura, N ;
Horino, Y ;
Fujii, K ;
Makihara, M ;
Hayakaya, J ;
Ohno, N .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1999, 149 (1-2) :77-80
[7]   Origin of White Luminescence in Ag-Eu Co-doped Oxyfluoride Glasses [J].
Guo, Hai ;
Li, JingJing ;
Li, Fang ;
Zhang, Hao .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (06) :J165-J168
[8]   Blue-white-green tunable luminescence from Ba2Gd2Si4O13:Ce3+,Tb3+ phosphors excited by ultraviolet light [J].
Guo, Hai ;
Zhang, Hao ;
Li, JingJing ;
Li, Fang .
OPTICS EXPRESS, 2010, 18 (26) :27257-27262
[9]   Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses [J].
Guo, Hai ;
Wang, XiaoFeng ;
Chen, JinDeng ;
Li, Fang .
OPTICS EXPRESS, 2010, 18 (18) :18900-18905
[10]   Color Tuning Luminescence of Ce3+/Mn2+/Tb3+-Triactivated Mg2Y8(SiO4)6O2 via Energy Transfer: Potential Single-Phase White-Light-Emitting Phosphors [J].
Li, Guogang ;
Geng, Dongling ;
Shang, Mengmeng ;
Zhang, Yang ;
Peng, Chong ;
Cheng, Ziyong ;
Lin, Jun .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (44) :21882-21892