A New General Synthetic Strategy for Phase-Pure Complex Functional Materials

被引:33
作者
Green, David C. [2 ]
Glatzel, Stefan [3 ]
Collins, Andrew M. [2 ]
Patil, Avinash J. [1 ]
Hall, Simon R. [2 ]
机构
[1] Univ Bristol, Sch Chem, Ctr Organized Matter Chemsitry, Bristol BS8 1TS, Avon, England
[2] Univ Bristol, Sch Chem, Complex Funct Mat Grp, Bristol BS8 1TS, Avon, England
[3] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany
基金
英国工程与自然科学研究理事会;
关键词
superconductors; piezoelectrics; phosphor; synthesis; ionic liquids; IONIC-LIQUID; GROWTH; FILMS;
D O I
10.1002/adma.201202683
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ability of ionic liquids to solvate inorganic salts completely has to date never been employed in the synthesis of complex inorganic materials. Here, we demonstrate that complex functional oxides, even those traditionally considered extremely difficult to synthesize in bulk, such as quinternary superconductors, are produced with no impurity phases and on timescales that are much shorter than other synthetic techniques.
引用
收藏
页码:5767 / 5772
页数:6
相关论文
共 29 条
[1]  
Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]
[2]   Multiferroic and magnetoelectric materials [J].
Eerenstein, W. ;
Mathur, N. D. ;
Scott, J. F. .
NATURE, 2006, 442 (7104) :759-765
[3]   The giant electromechanical response in ferroelectric relaxors as a critical phenomenon [J].
Kutnjak, Z. ;
Petzelt, J. ;
Blinc, R. .
NATURE, 2006, 441 (7096) :956-959
[4]   High-Tc superconducting materials for electric power applications [J].
Larbalestier, D ;
Gurevich, A ;
Feldmann, DM ;
Polyanskii, A .
NATURE, 2001, 414 (6861) :368-377
[5]  
Lawrence I. R., 2002, REPORT HIGH TEMPERAT
[6]   Facile Ionothermal Synthesis of Microporous and Mesoporous Carbons from Task Specific Ionic Liquids [J].
Lee, Je Seung ;
Wang, Xiqing ;
Luo, Huimin ;
Baker, Gary A. ;
Dai, Sheng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (13) :4596-+
[7]   Preparation of Inorganic Materials Using Ionic Liquids [J].
Ma, Zhen ;
Yu, Jihong ;
Dai, Sheng .
ADVANCED MATERIALS, 2010, 22 (02) :261-285
[8]  
Maiorov B, 2009, NAT MATER, V8, P398, DOI [10.1038/NMAT2408, 10.1038/nmat2408]
[9]  
Matthew Y. L., 2011, CHEM SCI, V2, P1491
[10]   Hydrophobic ionic liquids with strongly coordinating anions [J].
Mehdi, Hasan ;
Binnemans, Koen ;
Van Hecke, Kristof ;
Van Meervelt, Luc ;
Nockemann, Peter .
CHEMICAL COMMUNICATIONS, 2010, 46 (02) :234-236