Edge-hydroxylated Boron Nitride for Oxidative Dehydrogenation of Propane to Propylene

被引:33
作者
Shi, Lei
Wang, Dongqi
Song, Wei
Shao, Dan
Zhang, Wei-Ping
Lu, An-Hui
机构
[1] State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian
[2] Center for Multi-Disciplinary Research, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing
基金
中国国家自然科学基金;
关键词
boron; dehydrogenation; hydrocarbons; hydroxylation; nitrides;
D O I
10.1002/cctc.201700745
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The front cover artwork for Issue 10/2017 is provided by the Advanced Energy Materials and Catalysis Research Group, Dalian University of Technology and the Institute of High Energy Physics, Chinese Academy of Sciences. The image shows that a metal-free catalyst, edge hydroxylated boron nitride, can efficiently catalyze the oxidative dehydrogenation of propane to propylene with superior selectivity and negligible CO2 emission. See the Full Paper itself at https://doi.org/10.1002/cctc.201700004.
引用
收藏
页码:1720 / 1720
页数:1
相关论文
共 38 条
[1]   Subangstrom Edge Relaxations Probed by Electron Microscopy in Hexagonal Boron Nitride [J].
Alem, Nasim ;
Ramasse, Quentin M. ;
Seabourne, Che R. ;
Yazyev, Oleg V. ;
Erickson, Kris ;
Sarahan, Michael C. ;
Kisielowski, Christian ;
Scott, Andrew J. ;
Louie, Steven G. ;
Zettl, A. .
PHYSICAL REVIEW LETTERS, 2012, 109 (20)
[2]   High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr-Al pillared clay [J].
Andrea De Leon, Maria ;
De Los Santos, Carolina ;
Latronica, Luis ;
Maria Cesio, Ana ;
Volzone, Cristina ;
Castiglioni, Jorge ;
Sergio, Marta .
CHEMICAL ENGINEERING JOURNAL, 2014, 241 :336-343
[3]   DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR [J].
BECKE, AD .
PHYSICAL REVIEW A, 1988, 38 (06) :3098-3100
[4]   Band gap engineering by functionalization of BN sheet [J].
Bhattacharya, A. ;
Bhattacharya, S. ;
Das, G. P. .
PHYSICAL REVIEW B, 2012, 85 (03)
[5]   Tubes of rhombohedral boron nitride [J].
Bourgeois, L ;
Bando, Y ;
Sato, T .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2000, 33 (15) :1902-1908
[6]   Advanced Catalytic Dehydrogenation Technologies for Production of Olefins [J].
Bricker, Jeffery C. .
TOPICS IN CATALYSIS, 2012, 55 (19-20) :1309-1314
[7]   Catalytic synergy in the oxidative dehydrogenation of propane over MgVO catalysts [J].
Carrazan, SRG ;
Peres, C ;
Bernard, JP ;
Ruwet, M ;
Ruiz, P ;
Delmon, B .
JOURNAL OF CATALYSIS, 1996, 158 (02) :452-476
[8]   Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts [J].
Carrero, C. A. ;
Schloegl, R. ;
Wachs, I. E. ;
Schomaecker, R. .
ACS CATALYSIS, 2014, 4 (10) :3357-3380
[9]  
Caspary K. J., 2008, HDB HETEROGENEOUS CA, V6, P3206
[10]   Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? [J].
Cavani, F. ;
Ballarini, N. ;
Cericola, A. .
CATALYSIS TODAY, 2007, 127 (1-4) :113-131