High-performance aqueous sodium-ion/sulfur battery using elemental sulfur

被引:8
|
作者
Kumar, Mukesh [1 ]
Thakur, Neha [1 ]
Bordoloi, Ankur [2 ]
Yadav, Ashok Kumar [3 ]
Jha, Shambhunath N. [3 ]
Bhattacharyya, Dibyendu [3 ]
Mandal, Debaprasad [1 ]
Nagaiah, Tharamani C. [1 ]
机构
[1] Indian Inst Technol Ropar, Dept Chem, Rupnagar 140001, Punjab, India
[2] CSIR Indian Inst Petr CSIR IIP, Dehra Dun, Uttarakhand, India
[3] Bhabha Atom Res Ctr, Atom & Mol Phys Div, Mumbai 400094, Maharashtra, India
关键词
ION BATTERIES; CATHODE; POLYSULFIDES; CAPACITY; ANODE; HEXACYANOFERRATE; CONVERSION;
D O I
10.1039/d2ta02296f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Despite a promising outlook, the large-scale application of aqueous rechargeable sodium-ion batteries (ARSIBs) was impeded due to low-capacity electrode materials. Herein, we report a high capacity elemental sulfur-anode (S@NiVP/Pi-NCS) for aqueous rechargeable sodium ion/sulfur batteries using 70% of elemental sulfur, which delivers an outstanding capacity of 826 mA h g(-1) at 0.5C with an excellent cycling stability even at 10C and a negligible capacity decay with 0.03% sulfur loss per cycle even after 400 cycles. The NiVP/Pi-NCS host combines the merits of fast anchoring and high conductivity of the composite to achieve smooth anchoring-diffusion and conversion of sodium polysulfide. The superior anchoring and accelerated polysulfides redox kinetics were confirmed by various electrochemical studies and in situ spectro-electrochemical analysis. Chemical interaction with vanadium provides faster redox kinetics of polysulfide conversion and efficient anchoring as revealed by XPS and was further supported by XANES and EXAFS studies wherein the distortion at the V site and overlapping electronic states in the NiVP/Pi catalyst were observed. Further, a full cell battery assembled using S@NiVP/Pi-NCS anode and Na0.44MnO2 cathode demonstrates an excellent initial capacity of 756 mA h g(-1) based on S loading and 98.3 mA h g(-1) based upon total electrode weight with 95% of capacity retention even after 600 cycles and a remarkable energy density of 84 W h kg(-1) at 0.5C. Two full cells connected in series able to power LED demonstrate its practical application.
引用
收藏
页码:11394 / 11404
页数:11
相关论文
共 50 条
  • [41] Sulfur-doped carbon nanofibers as stable and high performance anode materials for sodium-ion batteries
    Lu, Mengwei
    Huang, Ying
    Du, Xianping
    Sheng, Xitong
    SUSTAINABLE ENERGY & FUELS, 2024, 8 (14): : 3056 - 3064
  • [42] High-sulfur-doped hard carbon for sodium-ion battery anodes with large capacity and high initial coulombic efficiency
    Wan, BaoShan
    Zhang, Haiyan
    Tang, Shuang
    Li, Shengkai
    Wang, Yan
    Wen, Daofeng
    Zhang, Minglu
    Li, Zhenghui
    SUSTAINABLE ENERGY & FUELS, 2022, 6 (18) : 4338 - 4345
  • [43] Simple synthesis of MoSSe heterojunction nanosphere for ultrafast kinetics and high-performance sodium-ion battery
    Yang, Haobin
    Tian, Chengxiang
    Wang, Jiashuo
    Cui, Songya
    Lin, Zhui
    Jiang, Ming
    Yan, Wensheng
    Wang, Donghua
    JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 1007
  • [44] A high-performance sodium-ion battery enhanced by macadamia shell derived hard carbon anode
    Zheng, Yuheng
    Wang, Yuesheng
    Lu, Yaxiang
    Hu, Yong-Sheng
    Li, Ju
    NANO ENERGY, 2017, 39 : 489 - 498
  • [45] Dual-phase MoS2 as a high-performance sodium-ion battery anode
    Wu, Junxiong
    Liu, Jiapeng
    Cui, Jiang
    Yao, Shanshan
    Ihsan-Ul-Haq, Muhammad
    Mubarak, Nauman
    Quattrocchi, Emanuele
    Ciucci, Francesco
    Kim, Jang-Kyo
    JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (04) : 2114 - 2122
  • [46] Investigation of sodium vanadate as a high-performance aqueous zinc-ion battery cathode
    Binghong She
    Lutong Shan
    Huijie Chen
    Jiang Zhou
    Xun Guo
    Guozhao Fang
    Xinxin Cao
    Shuquan Liang
    Journal of Energy Chemistry , 2019, (10) : 172 - 175
  • [47] Investigation of sodium vanadate as a high-performance aqueous zinc-ion battery cathode
    She, Binghong
    Shan, Lutong
    Chen, Huijie
    Zhou, Jiang
    Gun, Xun
    Fang, Guozhao
    Cao, Xinxin
    Liang, Shuquan
    JOURNAL OF ENERGY CHEMISTRY, 2019, 37 : 172 - 175
  • [48] THE SODIUM SULFUR BATTERY
    SUDWORTH, JL
    JOURNAL OF POWER SOURCES, 1984, 11 (1-2) : 143 - 154
  • [49] High-performance aqueous symmetric sodium-ion battery using NASICON-structured Na2VTi(PO4)3
    Hongbo Wang
    Tianran Zhang
    Chao Chen
    Min Ling
    Zhan Lin
    Shanqing Zhang
    Feng Pan
    Chengdu Liang
    Nano Research, 2018, 11 : 490 - 498
  • [50] High-performance aqueous symmetric sodium-ion battery using NASICON-structured Na2VTi(PO4)3
    Wang, Hongbo
    Zhang, Tianran
    Chen, Chao
    Ling, Min
    Lin, Zhan
    Zhang, Shanqing
    Pan, Feng
    Liang, Chengdu
    NANO RESEARCH, 2018, 11 (01) : 490 - 498