A Wide Range of Testing Results on an Excellent Lithium-Ion Cell Chemistry to be used as Benchmarks for New Battery Technologies

被引:326
作者
Harlow, Jessie E. [1 ,2 ]
Ma, Xiaowei [1 ,2 ]
Li, Jing [1 ,2 ]
Logan, Eric [1 ,2 ]
Liu, Yulong [1 ,2 ]
Zhang, Ning [1 ,2 ]
Ma, Lin [1 ,2 ]
Glazier, Stephen L. [1 ,2 ]
Cormier, Marc M. E. [1 ,2 ]
Genovese, Matthew [1 ,2 ]
Buteau, Samuel [1 ,2 ]
Cameron, Andrew [1 ,2 ]
Stark, Jamie E. [1 ,2 ]
Dahn, J. R. [1 ,2 ]
机构
[1] Dalhousie Univ, Dept Phys & Atmospher Sci, Halifax, NS B3H 4R2, Canada
[2] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
DIFFERENTIAL VOLTAGE ANALYSIS; ELECTROLYTE ADDITIVES; DEGRADATION MECHANISMS; SINGLE-CRYSTAL; HIGH-POWER; CALENDAR; CAPACITY; PRECISION; LIPO2F2; IMPACT;
D O I
10.1149/2.0981913jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We present a wide range of testing results on an excellent moderate-energy-density lithium-ion pouch cell chemistry to serve as benchmarks for academics and companies developing advanced lithium-ion and other "beyond lithium-ion" cell chemistries to (hopefully) exceed. These results are far superior to those that have been used by researchers modelling cell failure mechanisms and as such, these results are more representative of modern Li-ion cells and should be adopted by modellers. Up to three years of testing has been completed for some of the tests. Tests include long-term charge-discharge cycling at 20, 40 and 55 degrees C, long-term storage at 20, 40 and 55 degrees C, and high precision coulometry at 40 degrees C. Several different electrolytes are considered in this LiNi0.5Mn0.3Co0.2O2/graphite chemistry, including those that can promote fast charging. The reasons for cell performance degradation and impedance growth are examined using several methods. We conclude that cells of this type should be able to power an electric vehicle for over 1.6 million kilometers (1 million miles) and last at least two decades in grid energy storage. The authors acknowledge that other cell format-dependent loss, if any, (e.g. cylindrical vs. pouch) may not be captured in these experiments. (C) The Author(s) 2019. Published by ECS.
引用
收藏
页码:A3031 / A3044
页数:14
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