Reactive Extraction of Gallic Acid Using Trioctylamine and Tributyl Phosphate with Natural Oils

被引：4
作者：
Pandey, Shitanshu [1 ]
Wasewar, Kailas S. [2 ]
Datta, Dipaloy [3 ]
Kumar, Sushil [1 ]
机构：
[1] Motilal Nehru Natl Inst Technol Allahabad MNNIT, Chem Engn Dept, Prayagraj 211004, Uttar Pradesh, India
[2] Msvesvaraya Natl Inst Technol, Chem Engn Dept, Nagpur, Maharashtra, India
[3] Malaviya Natl Inst Technol, Chem Engn Dept, Jaipur, Rajasthan, India
来源：
CHEMICAL ENGINEERING & TECHNOLOGY | 2022年 / 45卷 / 03期
关键词：
Differential evolution; Gallic acid; Natural oils; Reactive extraction; AMINE; WATER; INTENSIFICATION;
D O I：
10.1002/ceat.202100449
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Experimental and theoretical perspectives of reactive extraction of gallic acid (GA) from aqueous solutions using tri-n-butyl phosphate (TBP) and tri-n-octylamine (TOA) as extractant dissolved in three nontoxic natural oils, namely, rice bran oil, sunflower oil, and soybean oil, are investigated. The solvent's extractability is observed in an order of sunflower oil > rice bran oil > soybean oil and rice bran oil > sunflower oil > soybean oil with TOA and TBP, respectively. The theoretical insights of reaction mechanisms for the extraction of GA are estimated in the form of overall equilibrium constants (K-E), stoichiometric coefficients (m), individual equilibrium constants (K-11, K-12, K-21), and concentrations (C-11, C-12, and C-21) of various complexes formed between extractant and acid.
引用
收藏
页码：526 / 534
页数：9
相关论文
共 28 条
  • [1] A new process for the management of olive oil mill waste water and recovery of natural antioxidants
    Agalias, Apostolis
    Magiatis, Prokopios
    Skaltsounis, Alexios-Leandros
    Mikros, Emmanuel
    Tsarbopoulos, Anthony
    Gikas, Evagelos
    Spanos, Ioannis
    Manios, Thrasyvoulos
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (07) : 2671 - 2676
  • [2] Banerjee D., 2007, RES J MICROBIOL, V2, P462, DOI [10.3923/jm.2007.462.468, DOI 10.3923/jm.2007.462.468]
  • [3] Cascaval D., 2004, Hemijska industrija, V58, P375, DOI DOI 10.2298/HEMIND0409375C
  • [4] Reactive Extraction of Picolinic Acid Using Tri-n-octylamine Dissolved in Different Diluents: Effect of Solvent Polarity
    Datta, Dipaloy
    Kumar, Sushil
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2015, 60 (09) : 2709 - 2716
  • [5] Status of the Reactive Extraction as a Method of Separation
    Datta, Dipaloy
    Kumar, Sushil
    Uslu, Hasan
    [J]. JOURNAL OF CHEMISTRY, 2015, 2015
  • [6] Intensification of picolinic acid extraction with tri-n-butylphosphate and tri-n-octylamine in three different diluents
    Datta, Dipaloy
    Uslu, Hasan
    Kumar, Sushil
    [J]. CHEMICAL ENGINEERING RESEARCH & DESIGN, 2015, 95 : 105 - 112
  • [7] Intensification of Citric Acid Extraction by a Mixture of Trioctylamine and Tridodecylamine in Different Diluents
    Datta, Dipaloy
    Asci, Yavuz Selim
    Tuyun, Amac Fatih
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2015, 60 (03) : 960 - 965
  • [8] Reactive Extraction of Glycolic Acid Using Tri-n-Butyl Phosphate and Tri-n-Octylamine in Six Different Diluents: Experimental Data and Theoretical Predictions
    Datta, Dipaloy
    Kumar, Sushil
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (05) : 3041 - 3048
  • [9] EXTRACTION PROCESSES FOR BIOPRODUCT SEPARATION
    HARTL, J
    MARR, R
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 1993, 28 (1-3) : 805 - 819
  • [10] Microbial production of gallic acid by modified solid state fermentation
    Kar, B
    Banerjee, R
    Bhattacharyya, BC
    [J]. JOURNAL OF INDUSTRIAL MICROBIOLOGY & BIOTECHNOLOGY, 1999, 23 (03) : 173 - 177
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