Lanthanide-Organic Frameworks with Uncoordinated Lewis Base Sites: Tunable Luminescence, Antibiotic Detection, and Anticounterfeiting

被引：35

作者：

Guo, Zhen-Hua ^{[1
]}

Zhang, Peng-Feng ^{[1
]}

Ma, Lu-Lu ^{[1
]}

Deng, Yu-Xin ^{[1
]}

Yang, Guo-Ping ^{[1
]}

Wang, Yao-Yu ^{[1
]}

机构：

[1] Northwest Univ, Coll Chem & Mat Sci, Shaanxi Key Lab Phys Inorgan Chem, Key Lab Synthet & Nat Funct Mol,Minist Educ, Xian 710127, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年 / 61卷 / 16期

关键词：

SENSITIVE DETECTION; SELECTIVE DETECTION; POLYMER; CO2; COORDINATION; ADSORPTION; EXTRACTION; SEPARATION; EXPLOSIVES; EMISSION;

D O I：

10.1021/acs.inorgchem.2c00224

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new isostructural lanthanide metal-organic frameworks (Ln-MOFs), {[Ln2(L)3DMA4]middot2DMA}n(1-Ln, whereLn = Eu, Tb, or EuxTb1-x), werefirst constructed via thesolvothermal reactions of 4,6-di(4-carboxyphenyl)pyrimidine andLn3+ions.1-Lnexhibits a 4-connected two-dimensional frameworkendowed with uncoordinated Lewis base sites. An exploration ofluminescence sensing demonstrated1-Eucan be used for theselectivity detection of dimetridazole and metronidazole antibioticsin other antibiotics, blood plasma, and urine, acting as anexceptional recyclable luminescent probe. More importantly, theluminescent inks of1-Lnare invisible, color adjustable, and stabilized, which may greatly improve their anticounterfeiting applications

引用

页码：6101 / 6109

页数：9

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