Electrospun zeolitic imidazolate framework-8/poly (lactic acid) nanofibers for pipette-tip micro-solid phase extraction of carbamate insecticides from environmental samples

被引:9
|
作者
Esrafili, Ali [1 ,2 ]
Ghambarian, Mahnaz [3 ]
Yousefi, Mahmood [1 ]
机构
[1] Iran Univ Med Sci, Sch Publ Hlth, Dept Environm Hlth Engn, Tehran, Iran
[2] Iran Univ Med Sci, Res Ctr Environm Hlth Technol, Tehran, Iran
[3] ACECR, Iranian Res & Dev Ctr Chem Ind, Tehran, Iran
关键词
Micro-solid phase extraction; Zeolitic imidazolate framework-8; Gas chromatography/mass spectrometry; Environmental water samples; PERFORMANCE LIQUID-CHROMATOGRAPHY; MICROEXTRACTION; FIBER; PESTICIDES;
D O I
10.1016/j.arabjc.2022.104124
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the present study, electrospun zeolitic imidazolate framework-8/poly(lactic acid) nanofibers were successfully synthesized and characterized as a potential nanosorbent for the pipette-tip micro-solid phase extraction of chlorpropham, pirimicarb, carbaryl, and methiocarb carbamate insecticides from environmental water samples. The extraction procedure was followed by gas chromatography/mass spectrometry separation and determination of the target analytes. All the effective parameters of the extraction procedure were optimized through the one variable at-a-time method. Thanks to the very simple extraction procedure as well as the application of electrospun nanofibers with high surface area, the four analytes were efficiently extracted with as lowest extraction times as practicable. Under the optimal conditions, the calibration plots of the analytes were obtained within broad linear dynamic ranges of 0.5 - 150 ng mL(-1) for chlorpropham and pirimicarb plus 1.0 - 175 ng mL(-1) for carbaryl and methiocarb, respectively. Besides, limits of detection as low as 0.2 and 0.15 ng mL(-1) for chlorpropham and pirimicarb, respectively, as well as 0.5 ng mL(-1) for carbaryl and methiocarb indicate the favorable sensitivity of the analytical procedure. The applicability of the developed method was evaluated by quantitative determination of the target analytes in four different environmental water samples. Relative recoveries higher than 88.0% shows the acceptable accuracy of the method in the quantitative determination of the four carbamate insecticides. (C) 2022 The Author(s). Published by Elsevier B.V. on behalf of King Saud University.
引用
收藏
页数:10
相关论文
共 34 条
  • [21] Determination of phthalate esters in environmental water by magnetic Zeolitic Imidazolate Framework-8 solid-phase extraction coupled with high-performance liquid chromatography
    Liu, Xiaomei
    Sun, Zhiwei
    Chen, Guang
    Zhang, Wanwan
    Cai, Yiping
    Kong, Rongmei
    Wang, Xiaoyan
    Suo, Yourui
    You, Jinmao
    JOURNAL OF CHROMATOGRAPHY A, 2015, 1409 : 46 - 52
  • [22] Novel semi-automated graphene nanosheets based pipette-tip assisted micro-solid phase extraction as eco-friendly technique for the rapid detection of emerging environmental pollutant in waters
    Tsai, Pei-Chien
    Pundi, Arul
    Brindhadevi, Kathirvel
    Ponnusamy, Vinoth Kumar
    Chemosphere, 2021, 276
  • [23] Chromium-based metal organic framework for pipette tip micro-solid phase extraction: an effective approach for determination of methyl and propyl parabens in wastewater and shampoo samples
    Kaykhaii, Massoud
    Hashemi, Sayyed Hossein
    Andarz, Fariba
    Piri, Amin
    Sargazi, Ghasem
    Boczkaj, Grzegorz
    BMC CHEMISTRY, 2021, 15 (01)
  • [24] Chromium-based metal organic framework for pipette tip micro-solid phase extraction: an effective approach for determination of methyl and propyl parabens in wastewater and shampoo samples
    Massoud Kaykhaii
    Sayyed Hossein Hashemi
    Fariba Andarz
    Amin Piri
    Ghasem Sargazi
    BMC Chemistry, 15
  • [25] Zeolitic imidazolate framework-8 modified magnetic halloysite nanotube-based solid phase extraction for the analysis of carbamate pesticides by ultra-high performance liquid chromatography tandem mass spectrometry
    Shi, Zhihong
    Tian, Yuehong
    Liu, Junjie
    Wu, Wenwen
    Gao, Sifan
    Zhang, Hongyi
    ANALYTICAL METHODS, 2022, 14 (45) : 4659 - 4668
  • [26] The Mesoporous Porphyrinic Zirconium Metal-Organic Framework for Pipette-Tip Solid-Phase Extraction of Mercury from Fish Samples Followed by Cold Vapor Atomic Absorption Spectrometric Determination
    Mohammad Reza Rezaei Kahkha
    Saba Daliran
    Ali Reza Oveisi
    Massoud Kaykhaii
    Zahra Sepehri
    Food Analytical Methods, 2017, 10 : 2175 - 2184
  • [27] The Mesoporous Porphyrinic Zirconium Metal-Organic Framework for Pipette-Tip Solid-Phase Extraction of Mercury from Fish Samples Followed by Cold Vapor Atomic Absorption Spectrometric Determination
    Rezaei Kahkha, Mohammad Reza
    Daliran, Saba
    Oveisi, Ali Reza
    Kaykhaii, Massoud
    Sepehri, Zahra
    FOOD ANALYTICAL METHODS, 2017, 10 (07) : 2175 - 2184
  • [28] Determination of benzomercaptans in environmental complex samples by combining zeolitic imidazolate framework-8-based solid-phase extraction and high-performance liquid chromatography with UV detection
    Martinez-Perez-Cejuela, Hector
    Mompo-Rosello, Oscar
    Crespi-Sanchez, Neus
    Palomino Cabello, Carlos
    Catala-Icardo, Monica
    Simo-Alfonso, Ernesto F.
    Manuel Herrero-Martinez, Jose
    JOURNAL OF CHROMATOGRAPHY A, 2020, 1631
  • [29] Water stability of zeolite imidazolate framework 8 and application to porous membrane-protected micro-solid-phase extraction of polycyclic aromatic hydrocarbons from environmental water samples
    Ge, Dandan
    Lee, Hian Kee
    JOURNAL OF CHROMATOGRAPHY A, 2011, 1218 (47) : 8490 - 8495
  • [30] Deep eutectic solvent-doped graphite as an efficient adsorbent for pipette tip micro-solid phase extraction of mitoxantrone from seawater, drug, urine and blood samples prior to its spectrophotometric determination
    Esmailiun, Mina
    Hashemi, Sayyed Hossein
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2024, 21 (03) : 689 - 698