Sulfur Containing High Refractive Index Poly(arylene Thioether)s and Poly(arylene Ether)s

被引：21

作者：

Mazumder, Kajari ^{[1
,2
]}

Komber, Hartmut ^{[2
]}

Bittrich, Eva ^{[2
]}

Voit, Brigitte ^{[2
,3
]}

Banerjee, Susanta ^{[1
]}

机构：

[1] Indian Inst Technol Kharagpur, Mat Sci Ctr, Kharagpur 721302, W Bengal, India

[2] Leibniz Inst Polymerforsch Dresden eV, D-01069 Dresden, Germany

[3] Tech Univ Dresden, Chair Organ Chem Polymers, D-01062 Dresden, Germany

来源：

MACROMOLECULES | 2022年 / 55卷 / 03期

关键词：

HYPERBRANCHED POLYMERS; HIGH TRANSPARENCY; LIGHT; REACTIVITY; SOLUBILITY; TRANSITION; POLYETHERS; SULFIDE); COATINGS;

D O I：

10.1021/acs.macromol.1c02097

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of novel sulfur containing high refractive index linear and branched poly(arylene thioether)s and linear poly(arylene ether)s were synthesized via nucleophilic substitution reactions. The sulfur content was varied in each polymer structure, and the physico-chemical properties of the polymer were investigated with respect to sulfur and aromatic content. The polymers prepared exhibited transparency as high as 90% in the visible region and an RI of more than 1.70 at 589 nm. These properties along with high thermal stability (T-d5% up to 530 degrees C), excellent mechanical properties with tensile strength as high as 63 MPa and Young's modulus being 2.33 GPa, and ease of processability into thin films make the prepared series of polymers good candidates to be successfully applied in opto-electronic devices.

引用

页码：1015 / 1029

页数：15

共 68 条

[21] Synthesise of Polythioether and Heat Resistant Property of Polythioether Sealants [J].

Guo Ruiyi ;

Zhang Jianzheng ;

Wu Songhua .

2014 ASIA-PACIFIC INTERNATIONAL SYMPOSIUM ON AEROSPACE TECHNOLOGY, APISAT2014, 2015, 99 :1234-1240

[22] FLEXIBLE LIGHT-EMITTING-DIODES MADE FROM SOLUBLE CONDUCTING POLYMERS [J].

GUSTAFSSON, G ;

CAO, Y ;

TREACY, GM ;

KLAVETTER, F ;

COLANERI, N ;

HEEGER, AJ .

NATURE, 1992, 357 (6378) :477-479

[23] POLY(ARYL ETHER PHENYLQUINOXALINES) [J].

HEDRICK, JL ;

LABADIE, JW .

MACROMOLECULES, 1990, 23 (06) :1561-1568

[24] Recent Progress in High Refractive Index Polymers [J].

Higashihara, Tomoya ;

Ueda, Mitsuru .

MACROMOLECULES, 2015, 48 (07) :1915-1929

[25] NONLINEAR STRUCTURE-REACTIVITY CORRELATIONS - ACYL TRANSFER BETWEEN SULFUR AND OXYGEN NUCLEOPHILES [J].

HUPE, DJ ;

JENCKS, WP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (02) :451-464

[26] High performance printed N and P-type OTFTs enabling digital and analog complementary circuits on flexible plastic substrate [J].

Jacob, S. ;

Abdinia, S. ;

Benwadih, M. ;

Bablet, J. ;

Chartier, I. ;

Gwoziecki, R. ;

Cantatore, E. ;

van Roermund, A. H. M. ;

Maddiona, L. ;

Tramontana, F. ;

Maiellaro, G. ;

Mariucci, L. ;

Rapisarda, M. ;

Palmisano, G. ;

Coppard, R. .

SOLID-STATE ELECTRONICS, 2013, 84 :167-178

[27] High refractive index and low-birefringence polyamides containing thiazole and naphthalene units [J].

Javadi, Ali ;

Najjar, Zahra ;

Bahadori, Saedeh ;

Vatanpour, Vahid ;

Malek, Ali ;

Abouzari-Lotf, Ebrahim ;

Shockravi, Abbas .

RSC ADVANCES, 2015, 5 (111) :91670-91682

[28] Sulfur containing optical plastics and its ophthalmic lenses applications [J].

Jha, G. S. ;

Seshadri, G. ;

Mohan, A. ;

Khandal, R. K. .

E-POLYMERS, 2008,

[29] Low-loss fluorinated poly(arylene ether sulfide) waveguides with high thermal stability [J].

Kang, JW ;

Kim, JP ;

Lee, WY ;

Kim, JS ;

Lee, JS ;

Kim, JJ .

JOURNAL OF LIGHTWAVE TECHNOLOGY, 2001, 19 (06) :872-875

[30] Properties of binary polyimide blends containing hexafluoroisopropylidene group [J].

Khalil, Muhammad ;

Saeed, Shaukat ;

Ahmad, Zahoor .

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2007, 44 (01) :55-63

← 1 2 3 4 5 6 7 →