A Metallic Niobium Nitride with Open Nanocavities for Surface-Enhanced Raman Spectroscopy

被引：13
作者：
Li, Jingbin [1 ]
Li, Junfang [1 ]
Yi, Wencai [2 ]
Yin, Meng [1 ]
Fu, Yanling [1 ]
Xi, Guangcheng [1 ]
机构：
[1] Chinese Acad Inspect & Quarantine, Key Lab Analyt Chem Consumer Prod, Beijing 100176, Peoples R China
[2] Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Peoples R China
来源：
ANALYTICAL CHEMISTRY | 2022年 / 94卷 / 42期
关键词：
QUANTITATIVE SERS; SINGLE-MOLECULE; NANOPARTICLES; SCATTERING; GRAPHENE;
D O I：
10.1021/acs.analchem.2c02691
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The construction of open hot-spot structures that facilitate the entry of analytes is crucial for surface-enhanced Raman spectroscopy. Here, metallic niobium nitride (NbN) three-dimensional (3D) hierarchical networks with open nanocavity structure are first found to exhibit a strong visible-light localized surface plasmon resonance (LSPR) effect and extraordinary surface-enhanced Raman scattering (SERS) performance. The unique nanocavity structure allows easy entry of molecules, promoting the utilization of electromagnetic hot spots. The NbN substrate has a lowest detection limit of 1.0 x 10(-12) M and a Raman enhancement factor (EF) of 1.4 x 10(8) for contaminants. Furthermore, the NbN hierarchical networks possess outstanding environmental durability, high signal reproducibility, and detection universality. The remarkable SERS sensitivity of the NbN substrate can be attributed to the joint effect of LSPR and interfacial charge transport (CT).
引用
收藏
页码：14635 / 14641
页数：7
相关论文
共 45 条
[1]   Large-Scale Hot Spot Engineering for Quantitative SERS at the Single-Molecule Scale [J].
Chen, Hung-Ying ;
Lin, Meng-Hsien ;
Wang, Chun-Yuan ;
Chang, Yu-Ming ;
Gwo, Shangjr .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (42) :13698-13705
[2]   Noble metal-comparable SERS enhancement from semiconducting metal oxides by making oxygen vacancies [J].
Cong, Shan ;
Yuan, Yinyin ;
Chen, Zhigang ;
Hou, Junyu ;
Yang, Mei ;
Su, Yanli ;
Zhang, Yongyi ;
Li, Liang ;
Li, Qingwen ;
Geng, Fengxia ;
Zhao, Zhigang .
NATURE COMMUNICATIONS, 2015, 6
[3]   Niobium Nitride Nb4N5 as a New High-Performance Electrode Material for Supercapacitors [J].
Cui, Houlei ;
Zhu, Guilian ;
Liu, Xiangye ;
Liu, Fengxin ;
Xie, Yian ;
Yang, Chongyin ;
Lin, Tianquan ;
Gu, Hui ;
Huang, Fuqiang .
ADVANCED SCIENCE, 2015, 2 (12)
[4]   Quantum and Thermal Phase Slips in Superconducting Niobium Nitride (NbN) Ultrathin Crystalline Nanowire: Application to Single Photon Detection [J].
Delacour, Cecile ;
Pannetier, Bernard ;
Villegier, Jean-Claude ;
Bouchiat, Vincent .
NANO LETTERS, 2012, 12 (07) :3501-3506
[5]   Molecular engineering of organic semiconductors enables noble metal-comparable SERS enhancement and sensitivity [J].
Demirel, Gokhan ;
Gieseking, Rebecca L. M. ;
Ozdemir, Resul ;
Kahmann, Simon ;
Loi, Maria A. ;
Schatz, George C. ;
Facchetti, Antonio ;
Usta, Hakan .
NATURE COMMUNICATIONS, 2019, 10 (1)
[6]   RAMAN-SPECTRA OF PYRIDINE ADSORBED AT A SILVER ELECTRODE [J].
FLEISCHMANN, M ;
HENDRA, PJ ;
MCQUILLAN, AJ .
CHEMICAL PHYSICS LETTERS, 1974, 26 (02) :163-166
[7]   General Surface-Enhanced Raman Spectroscopy Method for Actively Capturing Target Molecules in Small Gaps [J].
Ge, Meihong ;
Li, Pan ;
Zhou, Guoliang ;
Chen, Siyu ;
Han, Wei ;
Qin, Feng ;
Nie, Yuman ;
Wang, Yaoxiong ;
Qin, Miao ;
Huang, Guangyao ;
Li, Shaofei ;
Wang, Yongtao ;
Yang, Liangbao ;
Tian, Zhongqun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (20) :7769-7776
[8]   Multicomponent Plasmonic Nanoparticles: From Heterostructured Nanoparticles to Colloidal Composite Nanostructures [J].
Ha, Minji ;
Kim, Jae-Ho ;
You, Myunghwa ;
Li, Qian ;
Fan, Chunhai ;
Nam, Jwa-Min .
CHEMICAL REVIEWS, 2019, 119 (24) :12208-12278
[9]   A fast and robust algorithm for Bader decomposition of charge density [J].
Henkelman, Graeme ;
Arnaldsson, Andri ;
Jonsson, Hannes .
COMPUTATIONAL MATERIALS SCIENCE, 2006, 36 (03) :354-360
[10]   SURFACE RAMAN SPECTROELECTROCHEMISTRY .1. HETEROCYCLIC, AROMATIC, AND ALIPHATIC-AMINES ADSORBED ON ANODIZED SILVER ELECTRODE [J].
JEANMAIRE, DL ;
VANDUYNE, RP .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1977, 84 (01) :1-20
12345