Pickering emulsion of metal-free photoinduced electron transfer-ATRP stabilized by cellulose nanocrystals

被引：23
作者：
Wang, Guanglin [1 ]
Xi, Mengzhen [1 ]
Bai, Liangjiu [1 ]
Liang, Ying [1 ]
Yang, Lixia [1 ]
Wang, Wenxiang [1 ]
Chen, Hou [1 ]
Yang, Huawei [1 ]
机构：
[1] Ludong Univ, Key Lab High Performance & Funct Polymer Univ Sha, Collaborat Innovat Ctr Shandong Prov High Perform, Sch Chem & Mat Sci, Yantai 264025, Peoples R China
来源：
CELLULOSE | 2019年 / 26卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Cellulose nanocrystals; Atom transfer radical polymerization; Pickering emulsion; Photoinduced electron transfer ATRP; TRANSFER RADICAL POLYMERIZATION; HIGH-YIELD; EXTRACTION; POLYMERS;
D O I：
10.1007/s10570-019-02528-4
中图分类号：
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号：
0805 ; 080502 ; 0822 ;
摘要：
The development of metal-free photoinduced electron transfer-atom transfer radical polymerization (PET-ATRP) in Pickering emulsion by cellulose nanocrystals (CNCs) has successfully investigated. In the presence of ethyl 2-bromoisobutyrate (initiator) and triethylamine (additives), Eosin Y (photocatalyst) can effectively achieve the controllable polymerization of methyl methacrylate utilize CNCs as stabilizer. The polymerization in Pickering emulsion has relatively higher stability. The polymerizations of MMA showed typical living/controlled characteristics with controlled molecular weights (150,100-219,100g/mol) and low M-w/M-n (1.10-1.25). CNCs can not only be recycled, but also can be applicable as one of the most robust green emulsifier for PET-ATRP in Pickering emulsion. [GRAPHICS] .
引用
收藏
页码：5947 / 5957
页数：11
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