Two-Dimensional Coordination Polymer Showing Spin-Crossover Behavior with a 64 K Wide Hysteresis Loop

被引：4
作者：
Dong, Ya-Nan [1 ]
Liu, Zhi-Kun [1 ]
Xue, Jin-Peng [1 ]
Yao, Zi-Shuo [1 ]
Tao, Jun [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem & Chem Engn, Key Lab Cluster Sci, Minist Educ, Liangxiang Campus, Beijing 102488, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 50期
基金：
中国国家自然科学基金;
关键词：
THERMAL HYSTERESIS; MOLECULAR MATERIALS; SINGLE-CRYSTAL; TRANSITION; EPR; TRANSFORMATION; POLYMORPHS; STATE;
D O I：
10.1021/acs.inorgchem.2c03626
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A two-dimensional grid-like coordination polymer, [Fe(NCBH3)2(Py2ttz)2]center dot 4CHCl3 (1 center dot 4CHCl3, Py2ttz = 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole), showed one-step complete spin crossover with unexpectedly large hysteresis loop of 64 K wide and temperature-induced excited spin-state trapping effect below 91 K.
引用
收藏
页码：20232 / 20236
页数：5
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