Efficient Base Nickel-Catalyzed Hydrogenolysis of Furfural-DerivedTetrahydrofurfuryl Alcohol to 1,5-Pentanediol

被引：33

作者：

Al-Yusufi, Mohammed ^{[1
]}

Steinfeldt, Norbert ^{[1
]}

Eckelt, Reinhard ^{[1
]}

Atia, Hanan ^{[1
]}

Lund, Henrik ^{[1
]}

Bartling, Stephan ^{[1
]}

Rockstroh, Nils ^{[1
]}

Koeckritz, Angela ^{[1
]}

机构：

[1] Leibniz Inst Catalysis LIKAT, D-18059 Rostock, Germany

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2022年 / 10卷 / 15期

关键词：

1; 5-pentanediol; hydrogenolysis; transfer hydrogenolysis; ring opening; nickel; lanthanide hydroxide; furfural; tetrahydrofurfuryl alcohol; C-O HYDROGENOLYSIS; TETRAHYDROFURFURYL ALCOHOL; SELECTIVE HYDROGENOLYSIS; CYCLIC ETHERS; CHEMOSELECTIVE HYDROGENOLYSIS; BIOMASS; METAL; OXIDE; HYDROGENATION;

D O I：

10.1021/acssuschemeng.1c08340

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nickel(0) supported by strongly basic lanthanidehydroxides/oxyhydroxides (Ni-Ln, Ln = La, Pr, and Sm) is anefficient alternative noble metal-free catalyst for hydrogenolysis oftetrahydrofurfuryl alcohol (THFA) to 1,5-pentanediol (1,5-PeD) inorganic solvents (e.g., isopropanol). The catalytic performance ofNi-Lnwas studied both in batch and continuous modes. The highestyield of 1,5-PeD was 88% in a batch system and 73% in aflow systemusing40Ni-La reduced. Interestingly,40Ni-La reducedwas not onlyselective (>= 84%) but also stable in a long-term continuous run (386h). It is proposed that a metal support interface (Ni-Ln)isresponsible for cleaving the C-O bond of THFA via two initialsteps: deprotonation of THFA and activation of hydrogen. Addition-ally, transfer hydrogenolysis took place in the presence of H2insecondary alcohols, resulting in higher yields of 1,5-PeD under batch conditions. However, addition of H2had almost no influenceon catalyst selectivity to 1,5-PeD underflow conditions.

引用

页码：4954 / 4968

页数：15

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