共 33 条
Highly improved toluene gas-sensing performance of mesoporous Ag-anchored cobalt oxides nanowires
被引:23
|作者:
Yue, J. H.
[1
]
Wang, L.
[1
]
Xu, J. C.
[1
]
Jin, H. X.
[1
]
Hong, B.
[1
]
Jin, D. F.
[1
]
Gong, J.
[1
]
Peng, X. L.
[1
]
Ge, H. L.
[1
]
Wang, X. Q.
[1
]
机构:
[1] China Jiliang Univ, Coll Mat Sci & Chem, Hangzhou 310018, Peoples R China
关键词:
Ag-loading;
Microstructure;
Toluene gas;
Gas-sensing performance;
ORGANIC FRAMEWORK;
CARBON-MONOXIDE;
OPTICAL-PROPERTIES;
CO3O4;
NANOPARTICLES;
NANOCATALYSTS;
MECHANISM;
VOCS;
WO3;
D O I:
10.1016/j.apt.2022.103832
中图分类号:
TQ [化学工业];
学科分类号:
0817 ;
摘要:
Mesoporous cobalt oxides nanowires (Co3O4 NWs) were synthesized by the nanocasting method, and then Ag nanoparticles with the different content were anchored on the surface of Co3O4 NWs. The exper-imental results indicate that Ag nanoparticles hardly affect the morphology and microstructure of Co3O4 NWs and actually exist on the surface of Co3O4 NWs. It is worth mentioning that Ag-loading greatly improves the toluene gas-sensing performance of Ag-anchored Co3O4 NWs. The operating temperature of Ag-anchored Co3O4 NWs sensors decreases from 210 degrees C for Co3O4 NWs sensor to 190 degrees C, while the response to 100 ppm toluene gas increases 3-folds. Ag0.166-Co3O4 NWs sensor exhibits the best gas -sensing performance due to the optimal Ag-loading content. Ag nanoparticles not only provide more effective oxygen adsorption sites to reduce resistance in air, but also form metal-semiconductor hetero-junctions at the Ag/Co3O4 interface to increase resistance in toluene gas. In this way, Ag-loading can fur-ther improve the gas-sensing performance of mesoporous Ag-anchored Co3O4 NWs sensors to toluene gas.(c) 2022 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
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