Ultrathin MOF nanosheet-based resistive sensors for highly sensitive detection of methanol

被引:11
作者
Dai, Fangna [1 ]
Cui, Xiaoya [3 ]
Luo, Yuwei [1 ]
Zhang, Dongzhi [1 ]
Li, Nanjun [2 ]
Huang, Ying [4 ]
Peng, Yongwu [2 ]
机构
[1] China Univ Petr East China, Sch Mat Sci & Engn, 66 Changjiang West Rd, Qingdao 266580, Shandong, Peoples R China
[2] Zhejiang Univ Technol, Coll Mat Sci & Engn, Hangzhou 310014, Peoples R China
[3] Tsinghua Univ, Sch Life Sci, Beijing Adv Innovat Ctr Struct Biol, Minist Educ,Key Lab Prot Sci, Beijing 100084, Peoples R China
[4] Southwest Univ Sci & Technol, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC-FRAMEWORK; ELECTRODES;
D O I
10.1039/d2cc04230d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sensors with high-sensitivity for resistive methanol gas detection are highly desirable. Herein, we report newly designed ultrathin anionic metal-organic framework (MOF) nanosheets (NSs), with an average thickness of 10 nm and an electrical conductivity of 3.77 x 10(-4) S cm(-1). The ultrathin MOF NSs can be used as the active material in an electronic methanol gas sensor, which exhibits high sensitivity toward methanol gas at room temperature, i.e., high R-air/R-gas (363.2 at 100 ppm), fast gas response/recovery speed (6 s/2 s at 20 ppm), long-term stability, and superior cross-selectivity against other interfering gases.
引用
收藏
页码:11543 / 11546
页数:4
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