Solution-Processable liquid crystalline organic semiconductors based on 6-(Thiophen-2-yl)benzo[b]thiophene for organic thin-film transistors

Liquid crystalline organic semiconductors have garnered significant attention in the realm of organic thin-film transistors (OTFTs) due to their inherent controllability of phase and electrical properties with temperature variations. Typically, liquid crystalline semiconductors possess distinct structures comprising rigid anisotropic cores and flexible chains. Here, we sought to identify liquid crystalline semiconductor materials by appending a thiophene ring and octyl chain to the anisotropic 6-(thiophen-2-yl)benzo[b]thiophene (TBT) backbone. Among the investigated TBT derivatives, the compound featuring additional thiophene ring and octyl chains on both sides exhibited pronounced liquid crystalline characteristics, specifically the SmE phase. The optical, thermal, and electrical characteristics as well as thin film properties of the TBT derivatives were investigated. The TBT compound was employed through solution-shearing as an active layer for top-contact/bottom-gate OTFTs. The liquid-crystalline TBT (2,6-bis(5-octylthiophen-2-yl)benzo[b]thiophene) thin film annealed at low temperature (30 degrees C) showed hole mobility as high as 0.025 cm(2)/Vs and current on/off ratio of > 10(6). This results in a significant enhancement by an order of magnitude compared to the sample annealed at 70 degrees C in the SmE phase, and nearly a two-fold improvement compared to the performance observed in the sample annealed at 130 degrees C in the transition phase. The utilization of the TBT derivative as a p-channel material represents a significant step toward the development of novel liquid crystalline semiconductors.