Interaction laws of RE2O3 and CMAS and rare earth selection criterions for RE-containing thermal barrier coatings against CMAS attack

被引:26
作者
Guo, Lei [1 ,2 ]
Zhang, Bing [1 ]
Gao, Yuan [1 ]
Yan, Kai [3 ]
机构
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
[2] Minist Educ, Tianjin Key Lab Adv Joining Technol, Key Lab Adv Ceram & Machining Technol, Tianjin 300072, Peoples R China
[3] China Special Equipment Inspect & Res Inst, Key Lab Special Equipment Safety & Energy saving S, Beijing 100029, Peoples R China
关键词
Thermal barrier coatings; CMAS; Rare earth oxides; RE-apatite protective products; Interaction laws; MAGNESIUM-ALUMINA-SILICATE; MOLTEN VOLCANIC ASH; CORROSION BEHAVIOR; RESISTANT; TEMPERATURE; DEGRADATION; OXIDES; GLASS; INFILTRATION; STABILITY;
D O I
10.1016/j.corsci.2023.111689
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Thermal barrier coatings (TBCs) with higher rare earth (RE) contents are more resistant to CaO-MgO-Al2O3-SiO2 (CMAS) attack due to their reaction to form apatite protective products. In this study, the reaction behavior between RE2O3 and CMAS was investigated and their interaction laws were clarified, based on which three criterions for selecting RE dopants for RE-containing TBC materials are proposed: 1) favorable reaction product types and strong protective products formation kinetics, 2) low RE3+ solubility in molten CMAS, and 3) low wettability of residual mixture. Sm2O3 and Gd2O3 are demonstrated as the most attractive dopants for RE containing TBCs against CMAS attack.
引用
收藏
页数:10
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