Remarkable White Circularly Polarized Electroluminescence Based on Chiral Co-assembled Helix Nanofiber Emitters

被引：40

作者：

Zhang, Yu ^{[1
]}

Li, Yupeng ^{[2
,3
]}

Quan, Yiwu ^{[1
]}

Ye, Shanghui ^{[2
,3
]}

Cheng, Yixiang ^{[4
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Key Lab High Performance Polymer Mat & Technol, Minist Educ, Nanjing 210023, Peoples R China

[2] Nanjing Univ Posts & Telecommun, Natl Synergist Innovat Ctr Adv Mat SICAM, Key Lab Organ Elect & Informat Displays KLOEID, Nanjing 210023, Peoples R China

[3] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Natl Synergist Innovat Ctr Adv Mat SICAM, Nanjing 210023, Peoples R China

[4] Nanjing Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Adv Organ Mat, Nanjing 210023, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2023年 / 62卷 / 01期

基金：

中国国家自然科学基金;

关键词：

POLYMER;

D O I：

10.1002/anie.202214424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

White circularly polarized organic light-emitting diodes (CP-WOLEDs) are of great significance in potential lighting sources and full-color 3D displays. However, High-performance white CP-EL sources are almost unexplored. We have constructed full-color CP-EL devices based on chiral co-assemblies by using three achiral conjugated pyrene-based dyes (BP, w-WP and c-WP) doped with chiral binaphthyl-based enantiomers (S-/R-M) as the EMLs through an intermolecular chirality induction mechanism. (S-/R-M)(0.2)-(c-WP)(0.8) films exhibit regular helix nanofibers under annealing treatment and emit strong white CPL. Significantly, remarkable CP-WOLEDs based on (S-/R-M)(0.2)-(c-WP)(0.8 )were achieved with vertical bar g(EL)vertical bar values as high as 6.2x10(-2) and an excellent CRI of 98 at the CIE coordinates of (0.33, 0.33). These are the highest g(EL) and CRI values of reported CP-WOLEDs to date. This is the first achievement of CP-WOLEDs based on chiral co-assembled helix nanofiber emitters, and provides a valuable strategy with which to develop white CP-EL for future practical applications.

引用

页数：10