Preferential CO2 adsorption by an ultra-microporous zinc-aminotriazolato-acetate MOF

被引:11
|
作者
Singh, Piyush [1 ,2 ]
Singh, Himan Dev [1 ,2 ]
Menon, Abhijith Hari [1 ,2 ]
Vaidhyanathan, Ramanathan [1 ,2 ]
机构
[1] Indian Inst Sci Educ & Res, Dept Chem, Dr Homi Bhabha Rd, Pune 411008, India
[2] Indian Inst Sci Educ & Res, Ctr Energy Sci, Dr Homi Bhabha Rd, Pune 411008, India
关键词
CARBON-DIOXIDE; CAPTURE; FRAMEWORKS; SELECTIVITY;
D O I
10.1039/d3cc01157g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultramicroporous MOFs enable tight packing of the active functional groups, directly impacting the selective guest-framework interactions. MOFs with pores simultaneously lined by methyl and amine may serve as the ultimate humid CO2 sorbent. However, structural complexity prevents taking full advantage even in a simple zinc-triazolato-acetate layered-pillared MOF.
引用
收藏
页码:5559 / 5562
页数:4
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