A heterostructural MoS2QDs@UiO-66 nanocomposite for the highly efficient photocatalytic degradation of methylene blue under visible light and simulated sunlight

被引:15
作者
Aboraia, A. M. [1 ,9 ,10 ]
Al-omoush, Majd [2 ]
Solayman, Malak [2 ]
Saad, Hatem M. H. [3 ]
Khabiri, Gomaa [4 ]
Saad, Mohamed [5 ]
Alsulaim, Ghayah M. [6 ]
Soldatov, Alexander V. [2 ]
Ismail, Yasser A. M. [7 ]
Gomaa, H. [8 ]
机构
[1] Al Azhar Univ, Fac Sci, Dept Phys, Assiut 71542, Egypt
[2] Southern Fed Univ, Smart Mat Res Inst, Sladkova 178-24, Rostov Na Donu 344090, Russia
[3] Univ New South Wales, Capabil Syst Ctr Sch Engn & IT, Canberra, ACT, Australia
[4] Fayoum Univ, Fac Sci, Phys Dept, Al Fayyum 63514, Egypt
[5] King Khalid Univ, Fac Appl Med Sci, Dept Radiol Sci, POB 9004, Abha, Saudi Arabia
[6] King Faisal Univ, Fac Sci, Dept Chem, Al Hasa, Saudi Arabia
[7] Islamic Univ Madinah, Fac Sci, Dept Phys, Medina, Saudi Arabia
[8] Al Azhar Univ, Fac Sci, Dept Chem, Assiut 71542, Egypt
[9] Al Azhar Univ, Fac Sci, Phys Dept, Energy Storage Res Lab ESRL, Assiut 71542, Egypt
[10] New Assiut Technol Univ, Coll Ind & Energy Technol, New Assiut City, Assiut, Egypt
关键词
CRYSTAL VIOLET; PERFORMANCE; GRAPHENE;
D O I
10.1039/d3ra06299f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of recyclable photocatalysts with high activity and stability has piqued the interest of researchers in the field of wastewater treatment. In this study, an ultrasonic probe approach was used to immerse a sequence of heterojunctions formed by metal-organic frameworks (UiO-66) and different amounts of molybdenum disulfide quantum dots (MoS(2)QDs), resulting in a highly recyclable MoS(2)QDs@UiO-66 photocatalyst. Multiple advanced techniques, such as XPS, XRD, TEM, XRF, and UV-vis spectrophotometry, were used to characterize and confirm the successful preparation of UIO-66 impregnated with MoS(2)QDs. The results indicated that the best heterostructure catalyst exhibited superior efficiency in the photocatalytic degradation of methylene blue (MB) in water, achieving approximately 99% removal within 30 minutes under simulated sunlight, while approximately 97% removal under visible light. The outstanding photocatalytic performance is predominantly attributed to the photoinduced separation of carriers in this heterostructure system. This study proposes a unique, simple, and low-cost method for improving the degradation performance of organic contaminants in water.
引用
收藏
页码:34598 / 34609
页数:12
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